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Photo-induced structural transformation of C[60] single crystals and C[60] compounds under high pressure
http://hdl.handle.net/2241/6376
http://hdl.handle.net/2241/6376d2334a6a-c2ec-4a3c-9c27-4db97b90c9b6
| Item type | アイテムタイプT(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2007-07-25 | |||||
| タイトル | ||||||
| タイトル | Photo-induced structural transformation of C[60] single crystals and C[60] compounds under high pressure | |||||
| 言語 | ||||||
| 言語 | jpn | |||||
| 資源タイプ | ||||||
| 資源タイプ | doctoral thesis | |||||
| 著者 |
三谷, 武志
× 三谷, 武志 |
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| 抄録 | ||||||
| 内容記述 | Photo-induced structural transformation of C60 single crystal and its compounds has been investigated under high pressure up to around 30 GPa by means of optical measurements. Formation of three-dimensional C60 network structure was achieved by the photo-irradiation to C60 single crystals under high pressure. Iodine doping worked as a structural template of the photo-dimerization because C60 dimmers were selectively fabricated irrespective of magnitude of the pressure applied during photo-irradiation. Alkali metal doping completely suppressed the structural change of C60 molecules. Electronic and vibrational properties of C60 products which were photo-irradiated under pressure showed that structural transformation of C60 single crystals significantly depended on the pressure applied during the photo-irradiation. The dependences can be interpreted as imprints of contracted structures under pressure due to formation of intermolecular bonds whose number is continuously increased with the applied pressure. The number of intermolecular bond has been estimated by comparative analyses using high pressure optical properties of the C60 photopolymer which was photo-irradiated at ambient pressure. The analyses reveal that the number of the intermolecular bond increases up to about 5 with the applied pressure to 25 GPa. The activation energy of the photo-transformation at 3 GPa has been estimated to be 0.23 eV which is equivalent to the activation energy of the photo-polymerization at ambient pressure. Therefore, the interlinking mechanism can be considered to be a [2+2] cycloadditional scheme similar to the photo-polymerization at ambient pressure. The three-dimensional structure of the polymerized phase originates from the inherent randomness of the photo-polymerization of C60 molecules. Iodine doping effects on the photo-induced structural transformation have been investigated by Raman spectroscopy for iodine doped C60 compounds crystallized into FCC and hexagonal structures. The photo-irradiation to the two samples yielded only C60 dimmers irrespective of the applied pressure. The decomposition of the polyiodine molecules that exist in C60 lattice has close relationship with the dimerization of C60 molecules. Alkali metal doping effects have also been investigated with A3C60 and A6C60 compounds, where A denotes potassium and rubidium. In spite of some hopeful precedents, structural transformation of C60 was completely suppressed by alkali metal doping even though the AxC60 was subjected to the photo-irradiation at high pressures and high temperatures. | |||||
| 書誌情報 |
発行日 2004 |
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| アクセス権 | ||||||
| アクセス権 | open access | |||||
| 注記 | ||||||
| 内容記述 | Includes bibliographical references | |||||
| 注記 | ||||||
| 内容記述 | [60] is subscript | |||||
| 取得学位 | ||||||
| 学位名 | 博士（工学） | |||||
| 取得学位 | ||||||
| 学位名 | Doctor of Philosophy in Engineering | |||||
| 学位授与大学 | ||||||
| 学位授与機関名 | 筑波大学 | |||||
| 学位授与機関名 | University of Tsukuba | |||||
| 学位授与年度 | ||||||
| 内容記述 | 2003 | |||||
| 学位授与年月日 | ||||||
| 学位授与年月日 | 2004-03-25 | |||||
| 報告番号 | ||||||
| 学位授与番号 | 甲第3401号 | |||||
