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Synthesis of a pyrimidine-based new chiral inducer for construction of cholesteric liquid crystal electrolyte solution and its electrochemical polymerization, and stimulated emission like interference
http://hdl.handle.net/2241/119723
http://hdl.handle.net/2241/119723802e49f9-e2a0-4a7a-9ae3-6e355d35189b
名前 / ファイル | ライセンス | アクション |
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POLYMER_54-15.pdf (1.6 MB)
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Item type | Journal Article(1) | |||||
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公開日 | 2013-09-17 | |||||
タイトル | ||||||
タイトル | Synthesis of a pyrimidine-based new chiral inducer for construction of cholesteric liquid crystal electrolyte solution and its electrochemical polymerization, and stimulated emission like interference | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Wang, Aohan
× Wang, Aohan× Kawabata, Kohsuke× Kawashima, Hirotsugu× Goto, Hiromasa |
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著者別名 |
後藤, 博正
× 後藤, 博正 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Pyrimidine-based chiral compounds were successfully synthesized via Mitsunobu reaction. The chiral molecules with rigid molecular shape can function as chiral inducers (chiral dopant) to prepare cholesteric liquid crystal (CLC) electrolyte solutions. We carried out electrochemical polymerization in the CLC electrolyte solution thus prepared with the chiral inducer. The polymerization in the CLC afforded chiroptically active polymer films. The synthesis of the pyrimidine-based chiral inducer, electrochemical polymerization, and observation of a surface image of the polymer were carried out. It is noted that the polymer shows laser diffraction in the visible range due to a periodic pattern produced by imprinting of structural chirality of the CLC electrolyte solution. The laser diffraction patterns are multiple circles, implying occurrence of stimulated emission via periodic patterns of the cholesteric order. | |||||
書誌情報 |
Polymer 巻 54, 号 15, p. 3821-3827, 発行日 2013-07 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0032-3861 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00776983 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1016/j.polymer.2013.04.053 | |||||
権利 | ||||||
権利情報 | © 2013 Elsevier Ltd. NOTICE: this is the author’s version of a work that was accepted for publication in Polymer. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Polymer,54,15,2013 http://dx. doi.org/10.1016/j.polymer.2013.04.053. | |||||
著者版フラグ | ||||||
値 | author | |||||
出版者 | ||||||
出版者 | Elsevier Ltd. | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2241/119723 | |||||
識別子タイプ | HDL |