{"created":"2021-03-01T07:07:52.611626+00:00","id":29391,"links":{},"metadata":{"_buckets":{"deposit":"d7e55cba-4877-43e6-910e-41f29a827ebb"},"_deposit":{"id":"29391","owners":[],"pid":{"revision_id":0,"type":"depid","value":"29391"},"status":"published"},"_oai":{"id":"oai:tsukuba.repo.nii.ac.jp:00029391","sets":["117:496","3:62:5598:659"]},"item_5_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"15","bibliographicPageEnd":"3827","bibliographicPageStart":"3821","bibliographicVolumeNumber":"54","bibliographic_titles":[{"bibliographic_title":"Polymer"}]}]},"item_5_creator_3":{"attribute_name":"著者別名","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"後藤, 博正"}],"nameIdentifiers":[{},{},{}]}]},"item_5_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Pyrimidine-based chiral compounds were successfully synthesized via Mitsunobu reaction. The chiral molecules with rigid molecular shape can function as chiral inducers (chiral dopant) to prepare cholesteric liquid crystal (CLC) electrolyte solutions. We carried out electrochemical polymerization in the CLC electrolyte solution thus prepared with the chiral inducer. The polymerization in the CLC afforded chiroptically active polymer films. The synthesis of the pyrimidine-based chiral inducer, electrochemical polymerization, and observation of a surface image of the polymer were carried out. It is noted that the polymer shows laser diffraction in the visible range due to a periodic pattern produced by imprinting of structural chirality of the CLC electrolyte solution. The laser diffraction patterns are multiple circles, implying occurrence of stimulated emission via periodic patterns of the cholesteric order.","subitem_description_type":"Abstract"}]},"item_5_identifier_34":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2241/119723"}]},"item_5_publisher_27":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier Ltd."}]},"item_5_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.polymer.2013.04.053","subitem_relation_type_select":"DOI"}}]},"item_5_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"©  2013 Elsevier Ltd. NOTICE: this is the author’s version of a work that was accepted for publication in Polymer. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Polymer,54,15,2013   http://dx. doi.org/10.1016/j.polymer.2013.04.053."}]},"item_5_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_5_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0032-3861","subitem_source_identifier_type":"ISSN"}]},"item_5_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00776983","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Wang, Aohan"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kawabata, Kohsuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kawashima, Hirotsugu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Goto, Hiromasa"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2014-05-09"}],"displaytype":"detail","filename":"POLYMER_54-15.pdf","filesize":[{"value":"1.6 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"POLYMER_54-15.pdf","url":"https://tsukuba.repo.nii.ac.jp/record/29391/files/POLYMER_54-15.pdf"},"version_id":"66941051-d749-4526-a655-856f0fa46728"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of a pyrimidine-based new chiral inducer for construction of cholesteric liquid crystal electrolyte solution and its electrochemical polymerization, and stimulated emission like interference","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis of a pyrimidine-based new chiral inducer for construction of cholesteric liquid crystal electrolyte solution and its electrochemical polymerization, and stimulated emission like interference"}]},"item_type_id":"5","owner":"1","path":["496","659"],"pubdate":{"attribute_name":"公開日","attribute_value":"2013-09-17"},"publish_date":"2013-09-17","publish_status":"0","recid":"29391","relation_version_is_last":true,"title":["Synthesis of a pyrimidine-based new chiral inducer for construction of cholesteric liquid crystal electrolyte solution and its electrochemical polymerization, and stimulated emission like interference"],"weko_creator_id":"1","weko_shared_id":5},"updated":"2022-04-27T08:57:44.919972+00:00"}