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Substitution of K+ for Na+ induces a phase transition from high-spin (HS) phase with the electronic configuration of Co2+(t2g5eg2)-Fe3+(t2g5) to low-spin (LS) phase with the electronic configuration of Co3+(t2g6)-Fe2+(t2g6). At around room temperature, the HS phase (LS phase) is observed in the region of x\u22640.2(x\u22650.8) while two phases coexist in the intermediate-x region (0.2\u2264x\u22640.8). We interpreted the two-phase region in terms of intrinsic phase separation into small-x (Na+-rich) and large-x (K+-rich) regions because the cations can migrate within the crystal to minimize the total free energy. We further confirmed that absorption spectra in the infrared, visible and Co/Fe K edge regions are quantitatively reproduced by the phase-separation model.", "subitem_description_type": "Abstract"}]}, "item_5_identifier_34": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2241/104361"}]}, "item_5_publisher_27": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "American Physical Society"}]}, "item_5_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1103/PhysRevB.80.134101", "subitem_relation_type_select": "DOI"}}]}, "item_5_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u00a9 2009 The American Physical Society"}]}, "item_5_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_5_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1098-0121", "subitem_source_identifier_type": "ISSN"}]}, "item_5_source_id_9": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA11187113", "subitem_source_identifier_type": "NCID"}]}, "item_5_subject_20": {"attribute_name": "NII\u30b5\u30d6\u30b8\u30a7\u30af\u30c8", "attribute_value_mlt": [{"subitem_subject": "\u57fa\u790e\u5de5\u5b66\u30fb\u5fdc\u7528\u7269\u7406\u5b66", "subitem_subject_scheme": "Other"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Abe, Y."}], "nameIdentifiers": [{"nameIdentifier": "67218", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kim, J. E."}], "nameIdentifiers": [{"nameIdentifier": "67219", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Matsuda, T."}], "nameIdentifiers": [{"nameIdentifier": "67220", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shibata, T."}], "nameIdentifiers": [{"nameIdentifier": "67221", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tanida, H."}], "nameIdentifiers": [{"nameIdentifier": "67222", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Uruga, T."}], "nameIdentifiers": [{"nameIdentifier": "67223", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Moritomo, Y."}], "nameIdentifiers": [{"nameIdentifier": "67224", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2013-12-20"}], "displaytype": "detail", "download_preview_message": "", "filename": "PRB_80-13.pdf", "filesize": [{"value": "481.9 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 4819000, "url": {"label": "PRB_80-13.pdf", "url": "https://tsukuba.repo.nii.ac.jp/record/18659/files/PRB_80-13.pdf"}, "version_id": "b222431c-f90a-4030-a2bd-0b01338faa5f"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Phase separation driven by mobile cations in  (Na1\u2212xKx)0.35Co[Fe(CN)6]0.74\u22c5zH2O", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Phase separation driven by mobile cations in  (Na1\u2212xKx)0.35Co[Fe(CN)6]0.74\u22c5zH2O"}]}, "item_type_id": "5", "owner": "1", "path": ["117/484", "3/62/5598/82"], "permalink_uri": "http://hdl.handle.net/2241/104361", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2010-01-14"}, "publish_date": "2010-01-14", "publish_status": "0", "recid": "18659", "relation": {}, "relation_version_is_last": true, "title": ["Phase separation driven by mobile cations in  (Na1\u2212xKx)0.35Co[Fe(CN)6]0.74\u22c5zH2O"], "weko_shared_id": 5}