{"_buckets": {"deposit": "d169ecb2-d48f-40ff-8a8d-c03c9b4889b1"}, "_deposit": {"id": "54403", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "54403"}, "status": "published"}, "_oai": {"id": "oai:tsukuba.repo.nii.ac.jp:00054403"}, "item_5_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2019-10", "bibliographicIssueDateType": "Issued"}, "bibliographicPageStart": "4880", "bibliographicVolumeNumber": "10", "bibliographic_titles": [{}, {"bibliographic_title": "Nature Communications", "bibliographic_titleLang": "en"}]}]}, "item_5_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Hydrogen boride nanosheets (HB sheets) are facilely synthesized via ion-exchange treatment on magnesium diboride (MgB2) in an acetonitrile solution. Optical absorption and fluorescence spectra of HB sheets indicate that their bandgap energy is 2.8 eV. According to first-principles calculations, optical absorption seen at 2.8 eV is assigned to the electron transition between the sigma-bonding states of B and H orbitals. In addition, density functional theory (DFT) calculations suggest the other allowed transition from the s-bonding state of B and H orbitals to the antibonding state with the gap of 3.8 eV. Significant gaseous H-2 release is found to occur only under photoirradiation, which causes the electron transition from the s-bonding state to the antibonding state even under mild ambient conditions. The amount of H-2 released from the irradiated HB sheets is estimated to be 8 wt%, indicating that the sheets have a high H-2-storage capacity compared with previously reported metal H-2-storage materials.", "subitem_description_type": "Abstract"}]}, "item_5_publisher_27": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Nature Publishing Group"}]}, "item_5_relation_10": {"attribute_name": "PubMed\u756a\u53f7", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "31653945", "subitem_relation_type_select": "PMID"}}]}, "item_5_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1038/s41467-019-12903-1", "subitem_relation_type_select": "DOI"}}]}, "item_5_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u00a9 The Author(s) 2019"}, {"subitem_rights": "This article is licensed under a Creative CommonsAttribution 4.0 International License, which permits use, sharing,adaptation, distribution and reproduction in any medium or format, as long as you giveappropriate credit to the original author(s) and the source, provide a link to the CreativeCommons license, and indicate if changes were made. The images or other third partymaterial in this article are included in the article\u2019s Creative Commons license, unlessindicated otherwise in a credit line to the material. If material is not included in thearticle\u2019s Creative Commons license and your intended use is not permitted by statutoryregulation or exceeds the permitted use, you will need to obtain permission directly fromthe copyright holder. To view a copy of this license, visithttp://creativecommons.org/licenses/by/4.0/."}]}, "item_5_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_5_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "2041-1723", "subitem_source_identifier_type": "ISSN"}]}, "item_5_source_id_9": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA12645905", "subitem_source_identifier_type": "NCID"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "\u8fd1\u85e4, \u525b\u5f18"}, {"creatorName": "\u30b3\u30f3\u30c9\u30a6, \u30bf\u30ab\u30d2\u30ed", "creatorNameLang": "ja-Kana"}, {"creatorName": "KONDO, Takahiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "33", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "70373305", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://nrid.nii.ac.jp/ja/nrid/1000070373305"}, {"nameIdentifier": "0000000675", "nameIdentifierScheme": "\u7b51\u6ce2\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7", "nameIdentifierURI": "http://trios.tsukuba.ac.jp/researcher/0000000675"}]}, {"creatorNames": [{"creatorName": "Kawamura, Reiya", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "218631", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Cuong, Nguyen Thanh", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "218632", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fujita, Takeshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "218633", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ishibiki, Ryota", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "218634", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hirabayashi, Toru", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "218635", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamaguchi, Akira", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "218636", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Matsuda, Iwao", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "218637", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okada, Susumu", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "218638", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Miyauchi, Masahiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "218639", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-03-23"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "NC_10-4880.pdf", "filesize": [{"value": "1.6 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_6", "mimetype": "application/pdf", "size": 1600000.0, "url": {"label": "NC_10-4880", "url": "https://tsukuba.repo.nii.ac.jp/record/54403/files/NC_10-4880.pdf"}, "version_id": "8a61e844-b24a-421e-b35d-0a143207feaa"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Photoinduced hydrogen release from hydrogen boride sheets", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Photoinduced hydrogen release from hydrogen boride sheets", "subitem_title_language": "en"}]}, "item_type_id": "5", "owner": "1", "path": ["117/300", "3/62/5596/1866"], "permalink_uri": "http://hdl.handle.net/2241/00159825", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2020-03-23"}, "publish_date": "2020-03-23", "publish_status": "0", "recid": "54403", "relation": {}, "relation_version_is_last": true, "title": ["Photoinduced hydrogen release from hydrogen boride sheets"], "weko_shared_id": 5}