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Here we report a new methodology for realizing a three-dimensional (3D) dynamic probe of single-molecule conductance, which enables the elaborate 3D analysis of the conformational effect on molecular electronics, by the formation of a Si/single molecule/Si structure using scanning tunnelling microscopy (STM). The formation of robust covalent bonds between a molecule and Si electrodes, together with STM-related techniques, enables the stable and repeated control of the conformational modulation of the molecule. By 3D imaging of the conformational effect on a 1,4-diethynylbenzene molecule, a binary change in conductance with hysteresis is observed for the first time, which is considered to originate from a mechanically activated conformational change.", "subitem_description_type": "Abstract"}]}, "item_5_publisher_27": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Nature Publishing Group"}]}, "item_5_relation_10": {"attribute_name": "PubMed\u756a\u53f7", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "26439280", "subitem_relation_type_select": "PMID"}}]}, "item_5_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1038/ncomms9465", "subitem_relation_type_select": "DOI"}}]}, "item_5_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u00a9 2015 Macmillan Publishers Limited. All rights reserved. This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article\u2019s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/"}]}, "item_5_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_5_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "2041-1723", "subitem_source_identifier_type": "ISSN"}]}, "item_5_source_id_9": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA12645905", "subitem_source_identifier_type": "NCID"}]}, "item_5_subject_20": {"attribute_name": "NII\u30b5\u30d6\u30b8\u30a7\u30af\u30c8", "attribute_value_mlt": [{"subitem_subject": "\u7269\u7406\u5b66", "subitem_subject_scheme": "Other"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Nakamura, Miki"}], "nameIdentifiers": [{"nameIdentifier": "124379", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yoshida, Shoji"}], "nameIdentifiers": [{"nameIdentifier": "124380", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Katayama, Tomoki"}], "nameIdentifiers": [{"nameIdentifier": "124381", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Taninaka, Atsushi"}], "nameIdentifiers": [{"nameIdentifier": "124382", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Mera, Yutaka"}], "nameIdentifiers": [{"nameIdentifier": "124383", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okada, Susumu"}], "nameIdentifiers": [{"nameIdentifier": "124384", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Takeuchi, Osamu"}], "nameIdentifiers": [{"nameIdentifier": "124385", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shigekawa, Hidemi"}], "nameIdentifiers": [{"nameIdentifier": "124386", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-01-12"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "NC_6-8465.pdf", "filesize": [{"value": "5.2 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_6", "mimetype": "application/pdf", "size": 5200000.0, "url": {"label": "NC_6-8465", "url": "https://tsukuba.repo.nii.ac.jp/record/36541/files/NC_6-8465.pdf"}, "version_id": "e69d1c97-6cfd-4d11-9f66-e475e2c7154c"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Mechanically activated switching of Si-based single-molecule junction as imaged with three-dimensional dynamic probe", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Mechanically activated switching of Si-based single-molecule junction as imaged with three-dimensional dynamic probe"}]}, "item_type_id": "5", "owner": "1", "path": ["117/133", "117/135", "117/490", "117/1210", "117/801", "3/62/5596/1866"], "permalink_uri": "http://hdl.handle.net/2241/00132408", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2016-01-06"}, "publish_date": "2016-01-06", "publish_status": "0", "recid": "36541", "relation": {}, "relation_version_is_last": true, "title": ["Mechanically activated switching of Si-based single-molecule junction as imaged with three-dimensional dynamic probe"], "weko_shared_id": 5}