{"_buckets": {"deposit": "a89c05bd-a314-4d44-9b5c-3a9d94bef32f"}, "_deposit": {"id": "32107", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "32107"}, "status": "published"}, "_oai": {"id": "oai:tsukuba.repo.nii.ac.jp:00032107"}, "item_5_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2014-12", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "32", "bibliographicPageStart": "26", "bibliographicVolumeNumber": "148", "bibliographic_titles": [{"bibliographic_title": "Electrochimica acta"}]}]}, "item_5_creator_3": {"attribute_name": "\u8457\u8005\u5225\u540d", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "\u5289, \u559c\u6b63"}], "nameIdentifiers": [{"nameIdentifier": "109855", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "\u82b1\u7530, \u4fe1\u5b50"}], "nameIdentifiers": [{"nameIdentifier": "109856", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "\u77f3\u7530, \u653f\u7fa9"}], "nameIdentifiers": [{"nameIdentifier": "559", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "30272173", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://nrid.nii.ac.jp/ja/nrid/1000030272173"}, {"nameIdentifier": "0000001046", "nameIdentifierScheme": "\u7b51\u6ce2\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7", "nameIdentifierURI": "http://trios.tsukuba.ac.jp/researcher/0000001046"}]}]}, "item_5_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Capacity fading mechanism of pristine and FePO4-coated LiNi1/3Co1/3Mn1/3O2 has been studied by electrochemical and magnetic methods. Along with cycles, significant increase of cell polarization and charger transfer resistance (Rct), which mainly cause the capacity fading at the initial charge/discharge cycles, have been observed according to the cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) analysis. In comparison, the existence of FePO4 coating layer can effectively suppress the deterioration of surface polarization and increase of Rct at the interface of electrode/electrolyte. The coated sample suppress the decrease of Li+ diffusion coefficient with prolonged cycles according to the galvanostatic intermittent titration technique (GITT) tests. It also shows larger Weiss constants (fitting above 130 K) and lower blocking temperatures, which indicate the surface coating can suppress the deterioration of Li/Ni disorder upon repeated cycles. This study may give the researchers some light on understanding the capacity fading mechanism of LiNi1/3Co1/3Mn1/3O2 and the effects of surface coating layer, and thus, give help to the future designing of superior coating layers for layered cathode materials in Li-ion batteries.", "subitem_description_type": "Abstract"}]}, "item_5_publisher_27": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Elsevier"}]}, "item_5_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1016/j.electacta.2014.10.018", "subitem_relation_type_select": "DOI"}}]}, "item_5_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u00a9 2014 Elsevier Ltd."}, {"subitem_rights": "NOTICE: this is the author\u2019s version of a work that was accepted for publication in Electrochimica acta. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in PUBLICATION, 148,(2014) DOI:10.1016/j.electacta.2014.10.018 "}]}, "item_5_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_5_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0013-4686", "subitem_source_identifier_type": "ISSN"}]}, "item_5_source_id_9": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00633261", "subitem_source_identifier_type": "NCID"}]}, "item_5_subject_20": {"attribute_name": "NII\u30b5\u30d6\u30b8\u30a7\u30af\u30c8", "attribute_value_mlt": [{"subitem_subject": " \u30a8\u30cd\u30eb\u30ae\u30fc\u5de5\u5b66", "subitem_subject_scheme": "Other"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Liu, Xizheng"}], "nameIdentifiers": [{"nameIdentifier": "109848", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Li, De"}], "nameIdentifiers": [{"nameIdentifier": "109849", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Li, Huiqiao"}], "nameIdentifiers": [{"nameIdentifier": "109850", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Iyo, Akira"}], "nameIdentifiers": [{"nameIdentifier": "109851", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hanada, Nobuko"}], "nameIdentifiers": [{"nameIdentifier": "109852", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ishida, Masayoshi"}], "nameIdentifiers": [{"nameIdentifier": "109853", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Zhou, Haoshen"}], "nameIdentifiers": [{"nameIdentifier": "109854", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-01-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "EA_148.pdf", "filesize": [{"value": "2.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 2100000.0, "url": {"label": "EA_148", "url": "https://tsukuba.repo.nii.ac.jp/record/32107/files/EA_148.pdf"}, "version_id": "34974829-037e-4927-ac53-08f381e532e8"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Study on the capacity fading of pristine and FePO4 coated LiNi1/3Co1/3Mn1/3O2 by Electrochemical and Magnetical techniques", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Study on the capacity fading of pristine and FePO4 coated LiNi1/3Co1/3Mn1/3O2 by Electrochemical and Magnetical techniques"}]}, "item_type_id": "5", "owner": "1", "path": ["152/1725", "152/2912", "3/62/5587/2024"], "permalink_uri": "http://hdl.handle.net/2241/00122981", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2015-01-22"}, "publish_date": "2015-01-22", "publish_status": "0", "recid": "32107", "relation": {}, "relation_version_is_last": true, "title": ["Study on the capacity fading of pristine and FePO4 coated LiNi1/3Co1/3Mn1/3O2 by Electrochemical and Magnetical techniques"], "weko_shared_id": 5}