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Synthesis and characterization of a novel donor–acceptor–donor chiral inducer and its application in electrochemical polymerization
http://hdl.handle.net/2241/00124534
http://hdl.handle.net/2241/00124534b6a1d0d4-fd09-485a-8711-b743473ee109
名前 / ファイル | ライセンス | アクション |
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JMCC_3-9 (1.6 MB)
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Item type | Journal Article(1) | |||||
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公開日 | 2015-05-13 | |||||
タイトル | ||||||
タイトル | Synthesis and characterization of a novel donor–acceptor–donor chiral inducer and its application in electrochemical polymerization | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Dong, Jiuchao
× Dong, Jiuchao× Kawabata, Kohsuke× Goto, Hiromasa |
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著者別名 |
後藤, 博正
× 後藤, 博正 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A novel chiral inducer having a donor–acceptor–donor structure was synthesized. Its rigid structure allows an increase of miscibility and helical twisting power for the host liquid crystal. The donor–acceptor–donor structure allows visible light absorption. Electrochemical polymerization of an achiral monomer was performed in a cholesteric liquid crystal induced by the inducer. The chiral inducer molecules alone showed right-handed helical aggregation in the solid state, while the inducer produces a left-handed helical arrangement of cholesteric liquid crystals in a nematic liquid crystal. The resultant conjugated polymer films showed circular dichroism and left-handed helical aggregation. Film surfaces displayed a periodic convex–concave structure that was transcribed from the fingerprint texture of the cholesteric liquid crystal electrolytes during the polymerization process. | |||||
書誌情報 |
Journal of materials chemistry. C 巻 3, 号 9, p. 2024-2032, 発行日 2015-03 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 2050-7526 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA12605026 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1039/C4TC02489C | |||||
権利 | ||||||
権利情報 | © The Royal Society of Chemistry 2015 | |||||
著者版フラグ | ||||||
値 | author | |||||
出版者 | ||||||
出版者 | The Royal Society of Chemistry |