{"created":"2021-03-01T07:36:46.941564+00:00","id":55768,"links":{},"metadata":{"_buckets":{"deposit":"cbf761cc-dda6-4d1c-9b77-e3056c5430d9"},"_deposit":{"id":"55768","owners":[],"pid":{"revision_id":0,"type":"depid","value":"55768"},"status":"published"},"_oai":{"id":"oai:tsukuba.repo.nii.ac.jp:00055768","sets":["117:300","117:4917","3:62:5595:8062"]},"item_5_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"7","bibliographicPageEnd":"267","bibliographicPageStart":"261","bibliographicVolumeNumber":"8","bibliographic_titles":[{},{"bibliographic_title":"Materials Research Letters","bibliographic_titleLang":"en"}]}]},"item_5_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Tetratitanium heptoxide, Ti4O7, is known to exhibit a two-step phase transition from the charge-delocalized to charge-localized phase and the charge-disordered to charge-ordered phase around 150 K and 130 K, respectively. Herein, a nanoscopic effect of the Ti4O7 phase transition is studied. A one-step phase transition from the charge-delocalized to charge-localized phase is realized in Ti4O7 nanocrystals where the transition from the charge-disordered to charge-ordered phase is suppressed. Perturbation to the free energy by the surface energy can explain this anomalous phase transition. The present nanoscopic effect, which can control cooperativity in phase transitions, should contribute to develop advanced switching materials.","subitem_description_type":"Abstract"}]},"item_5_publisher_27":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Taylor & Francis"}]},"item_5_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1080/21663831.2020.1743788","subitem_relation_type_select":"DOI"}}]},"item_5_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2020 The Author(s). Published by Informa UK Limited, trading as Taylor & Francis Group This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited."}]},"item_5_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_5_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2166-3831","subitem_source_identifier_type":"ISSN"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"所, 裕子"},{"creatorName":"トコロ, ヒロコ","creatorNameLang":"ja-Kana"},{"creatorName":"TOKORO, Hiroko","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"近藤, 剛弘"},{"creatorName":"コンドウ, タカヒロ","creatorNameLang":"ja-Kana"},{"creatorName":"KONDO, Takahiro","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Araki, Yusuke","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nagata, Iori","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Imoto, Kenta","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ohkoshi, Shin-ichi","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-09-04"}],"displaytype":"detail","filename":"MRL_8-7.pdf","filesize":[{"value":"2.8 MB"}],"format":"application/pdf","licensetype":"license_6","mimetype":"application/pdf","url":{"label":"MRL_8-7","url":"https://tsukuba.repo.nii.ac.jp/record/55768/files/MRL_8-7.pdf"},"version_id":"cb29a464-15d1-4f74-bd3b-2e0d38938467"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of nanosize tetratitanium heptoxide and its anomalous phase transition","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis of nanosize tetratitanium heptoxide and its anomalous phase transition","subitem_title_language":"en"}]},"item_type_id":"5","owner":"1","path":["300","4917","8062"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-09-04"},"publish_date":"2020-09-04","publish_status":"0","recid":"55768","relation_version_is_last":true,"title":["Synthesis of nanosize tetratitanium heptoxide and its anomalous phase transition"],"weko_creator_id":"1","weko_shared_id":5},"updated":"2022-04-27T09:30:35.547454+00:00"}