{"created":"2021-03-01T07:35:46.467068+00:00","id":54893,"links":{},"metadata":{"_buckets":{"deposit":"53d77a1e-28f9-4d28-b85d-95c1b678c90d"},"_deposit":{"created_by":188,"id":"54893","owners":[188],"pid":{"revision_id":0,"type":"depid","value":"54893"},"status":"published"},"_oai":{"id":"oai:tsukuba.repo.nii.ac.jp:00054893","sets":["1722922372414:117:1221","1722922372414:117:500","3:1722557955661:5296:8005"]},"author_link":["381","154","220322"],"item_1644910766877":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_5_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"5","bibliographicPageEnd":"3397","bibliographicPageStart":"3390","bibliographicVolumeNumber":"10","bibliographic_titles":[{"bibliographic_title":"ACS Catalysis","bibliographic_titleLang":"en"}]}]},"item_5_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The mechanism of the Pd/Ag dual-catalyzed cross-dehydrogenative coupling (CDC) between perfluoroarenes and thiophenes was clarified. The exact role of the catalytic resting state of the homo-biaryl-Pd(II) complex, which was previously overlooked in Pd/Ag dual-catalyzed CDC, was carefully investigated. Detailed experimental studies indicated that a homo-biaryl-Pd(II) complex occurred in the catalytic off-cycle as a resting state and prevented the homocoupling of perfluoroarenes. In addition, these studies indicated that the C–H bond activation steps of perfluoroarenes and thiophenes proceeded by different mechanisms. While the C–H bond of perfluoroarenes was immediately activated by Ag(I) salts, the C–H bond of thiophenes was activated by the Pd(II) catalyst. Kinetic studies revealed that the Pd(II)–C–H activation of thiophenes is most likely the rate-determining step.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_5_publisher_27":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society","subitem_publisher_language":"en"}]},"item_5_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acscatal.9b05326","subitem_relation_type_select":"DOI"}}]},"item_5_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2020 American Chemical Society","subitem_rights_language":"en"},{"subitem_rights":"This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society after peer review and technical editing by the publisher.  To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acscatal.9b05326.","subitem_rights_language":"en"}]},"item_5_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2155-5435","subitem_source_identifier_type":"EISSN"}]},"item_5_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12599706","subitem_source_identifier_type":"NCID"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"桑原, 純平","creatorNameLang":"ja"},{"creatorName":"クワバラ, ジュンペイ","creatorNameLang":"ja-Kana"},{"creatorName":"KUWABARA, Junpei","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"381","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"70466655","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/nrid/1000070466655"},{"nameIdentifier":"0000000760","nameIdentifierScheme":"筑波大学研究者総覧","nameIdentifierURI":"http://trios.tsukuba.ac.jp/researcher/0000000760"}]},{"creatorNames":[{"creatorName":"神原, 貴樹","creatorNameLang":"ja"},{"creatorName":"カンバラ, タカキ","creatorNameLang":"ja-Kana"},{"creatorName":"KANBARA, Takaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"154","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"90204809","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/nrid/1000090204809"},{"nameIdentifier":"0000000761","nameIdentifierScheme":"筑波大学研究者総覧","nameIdentifierURI":"http://trios.tsukuba.ac.jp/researcher/0000000761"}]},{"creatorNames":[{"creatorName":"Shimoyama, Yuto","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"220322","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-04-01"}],"displaytype":"detail","filename":"ACSCatal_10-5.pdf","filesize":[{"value":"727.7 kB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://tsukuba.repo.nii.ac.jp/record/54893/files/ACSCatal_10-5.pdf"},"version_id":"b04cb555-6425-4cbd-9ea5-fc4e876190ca"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Mechanistic Study of Pd/Ag Dual-Catalyzed Cross-Dehydrogenative Coupling of Perfluoroarenes with Thiophenes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Mechanistic Study of Pd/Ag Dual-Catalyzed Cross-Dehydrogenative Coupling of Perfluoroarenes with Thiophenes","subitem_title_language":"en"}]},"item_type_id":"5","owner":"188","path":["500","1221","8005"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-07-06"},"publish_date":"2020-07-06","publish_status":"0","recid":"54893","relation_version_is_last":true,"title":["Mechanistic Study of Pd/Ag Dual-Catalyzed Cross-Dehydrogenative Coupling of Perfluoroarenes with Thiophenes"],"weko_creator_id":"188","weko_shared_id":-1},"updated":"2024-07-09T05:43:26.190389+00:00"}