{"created":"2021-03-01T07:34:22.085137+00:00","id":53651,"links":{},"metadata":{"_buckets":{"deposit":"38c279f0-ee6a-4b4f-9de9-5893801e6e2b"},"_deposit":{"id":"53651","owners":[],"pid":{"revision_id":0,"type":"depid","value":"53651"},"status":"published"},"_oai":{"id":"oai:tsukuba.repo.nii.ac.jp:00053651","sets":["117:1707","3:62:5598:1879"]},"item_5_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3","bibliographicPageEnd":"457","bibliographicPageStart":"447","bibliographicVolumeNumber":"80","bibliographic_titles":[{},{"bibliographic_title":"Pure and Applied Chemistry","bibliographic_titleLang":"en"}]}]},"item_5_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The synthesis, crystal structure, and characterization of a silicon-silicon triply bonded species, disilyne with two bis[bis(trimethylsilyl)methyl]isopropylsilyl substituents, are described. The nature of the sp-hybridized silicon atoms is discussed from the viewpoint of spectroscopic results and theoretical calculations. The reactivity of the disilyne with alkali metals, tBuLi, and π-bonded compounds such as cis- and trans-2-butenes and phenylacetylene is also described.","subitem_description_type":"Abstract"}]},"item_5_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"International Symposium on Novel Aromatic Compounds (ISNA-12), International Symposium on Novel Aromatic Compounds, ISNA, Novel Aromatic Compounds, 12th, Awaji Island, Japan, 2007-07-22–2007-07-27","subitem_description_type":"Other"}]},"item_5_publisher_27":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"International Union of Pure and Applied Chemistry"}]},"item_5_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1351/pac200880030447","subitem_relation_type_select":"DOI"}}]},"item_5_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2008 IUPAC"}]},"item_5_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_5_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0033-4545","subitem_source_identifier_type":"ISSN"}]},"item_5_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00797859","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"関口, 章"},{"creatorName":"セキグチ, アキラ","creatorNameLang":"ja-Kana"},{"creatorName":"SEKIGUCHI, Akira","creatorNameLang":"en"}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-12-03"}],"displaytype":"detail","filename":"PAC_80-3.pdf","filesize":[{"value":"579.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"PAC_80-3","url":"https://tsukuba.repo.nii.ac.jp/record/53651/files/PAC_80-3.pdf"},"version_id":"62754d7f-469c-45b6-ad4d-b5826f2ef41f"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Disilyne with a silicon-silicon triple bond: A new entry to multiple bond chemistry","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Disilyne with a silicon-silicon triple bond: A new entry to multiple bond chemistry","subitem_title_language":"en"}]},"item_type_id":"5","owner":"1","path":["1707","1879"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-12-03"},"publish_date":"2019-12-03","publish_status":"0","recid":"53651","relation_version_is_last":true,"title":["Disilyne with a silicon-silicon triple bond: A new entry to multiple bond chemistry"],"weko_creator_id":"1","weko_shared_id":5},"updated":"2022-04-27T09:27:38.957902+00:00"}