@article{oai:tsukuba.repo.nii.ac.jp:00053651, author = {関口, 章 and SEKIGUCHI, Akira}, issue = {3}, journal = {Pure and Applied Chemistry}, month = {Mar}, note = {The synthesis, crystal structure, and characterization of a silicon-silicon triply bonded species, disilyne with two bis[bis(trimethylsilyl)methyl]isopropylsilyl substituents, are described. The nature of the sp-hybridized silicon atoms is discussed from the viewpoint of spectroscopic results and theoretical calculations. The reactivity of the disilyne with alkali metals, tBuLi, and π-bonded compounds such as cis- and trans-2-butenes and phenylacetylene is also described., International Symposium on Novel Aromatic Compounds (ISNA-12), International Symposium on Novel Aromatic Compounds, ISNA, Novel Aromatic Compounds, 12th, Awaji Island, Japan, 2007-07-22–2007-07-27}, pages = {447--457}, title = {Disilyne with a silicon-silicon triple bond: A new entry to multiple bond chemistry}, volume = {80}, year = {2008}, yomi = {セキグチ, アキラ} }