{"created":"2021-03-01T07:27:59.202461+00:00","id":47932,"links":{},"metadata":{"_buckets":{"deposit":"8b4ba469-0c27-4adc-91cb-7cda8d0736c8"},"_deposit":{"id":"47932","owners":[],"pid":{"revision_id":0,"type":"depid","value":"47932"},"status":"published"},"_oai":{"id":"oai:tsukuba.repo.nii.ac.jp:00047932","sets":["117:1207","117:1706","117:2918","3:62:5613:7044"]},"item_5_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-08","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"14","bibliographicPageEnd":"615","bibliographicPageStart":"611","bibliographicVolumeNumber":"644","bibliographic_titles":[{"bibliographic_title":"Zeitschrift für anorganische und allgemeine Chemie"}]}]},"item_5_creator_3":{"attribute_name":"著者別名","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"石塚, 智也"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"小谷, 弘明"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"小島, 隆彦"}],"nameIdentifiers":[{},{},{}]}]},"item_5_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Two novel RuII complexes, having 2,2′‐bipyridyl and a pincer‐type methylene‐bridged N‐heterocyclic carbene (NHC) ligand, were synthesized and characterized to evaluate the effects of structural features of the complexes on their redox and photochemical properties. The methylene‐bridged NHC ligand coordinated in a meridional manner and the isopropyl groups on the NHC rings exhibited intramolecular CH/π interaction with the 2,2′‐bipyridyl ligand, which played a role to strongly maintain the distorted ligand structure. In addition, the two Ru complexes exhibited reversible redox waves in the cyclic voltammograms and they were oxidized by an electron‐transfer oxidant to afford RuIII complexes, which were characterized by EPR spectroscopy and theoretical analyses.","subitem_description_type":"Abstract"}]},"item_5_publisher_27":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley"}]},"item_5_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/zaac.201800104","subitem_relation_type_select":"DOI"}}]},"item_5_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer-reviewed version of the following article: ZAAC Volume644, Issue14, Pages 611-615 which has been published in final form at https://doi.org/10.1002/zaac.201800104. This article may be used for non-commercial purposes in accordance with Wiley-VCH Terms and Conditions for Self-Archiving."},{"subitem_rights":"© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim"}]},"item_5_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_5_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00442313","subitem_source_identifier_type":"ISSN"}]},"item_5_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00894185","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shimoyama, Yoshihiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ishizuka, Tomoya"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kotani, Hiroaki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kojima, Takahiko"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-09-01"}],"displaytype":"detail","filename":"ZAAC_644-14.pdf","filesize":[{"value":"490.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ZAAC_644-14","url":"https://tsukuba.repo.nii.ac.jp/record/47932/files/ZAAC_644-14.pdf"},"version_id":"6b4579ca-a94a-424b-b3e0-1a245d0ad1de"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Ruthenium(II) Complexes Having a Pincer‐Type Ligand with Two N‐Heterocyclic Carbene Moieties","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Ruthenium(II) Complexes Having a Pincer‐Type Ligand with Two N‐Heterocyclic Carbene Moieties"}]},"item_type_id":"5","owner":"1","path":["1706","1207","2918","7044"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-10-01"},"publish_date":"2018-10-01","publish_status":"0","recid":"47932","relation_version_is_last":true,"title":["Ruthenium(II) Complexes Having a Pincer‐Type Ligand with Two N‐Heterocyclic Carbene Moieties"],"weko_creator_id":"1","weko_shared_id":5},"updated":"2022-04-27T09:20:00.775376+00:00"}