{"created":"2021-03-01T07:27:48.189718+00:00","id":47757,"links":{},"metadata":{"_buckets":{"deposit":"39e30e2c-0bf1-4d83-8489-3d4294020df0"},"_deposit":{"id":"47757","owners":[],"pid":{"revision_id":0,"type":"depid","value":"47757"},"status":"published"},"_oai":{"id":"oai:tsukuba.repo.nii.ac.jp:00047757","sets":["117:1448","3:62:5296:7096"]},"item_5_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-11","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageStart":"1700317","bibliographicVolumeNumber":"5","bibliographic_titles":[{"bibliographic_title":"Advanced Science"}]}]},"item_5_creator_3":{"attribute_name":"著者別名","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"石井, 宏幸"}],"nameIdentifiers":[{},{},{}]}]},"item_5_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Printed and flexible electronics requires solution‐processable organic semiconductors with a carrier mobility (μ) of ≈10 cm2 V−1 s−1 as well as high chemical and thermal durability. In this study, chryseno[2,1‐b:8,7‐b′]dithiophene (ChDT) and its derivatives, which have a zigzag‐elongated fused π‐electronic core (π‐core) and a peculiar highest occupied molecular orbital (HOMO) configuration, are reported as materials with conceptually new semiconducting π‐cores. ChDT and its derivatives are prepared by a versatile synthetic procedure. A comprehensive investigation reveals that the ChDT π‐core exhibits increasing structural stability in the bulk crystal phase, and that it is unaffected by a variation of the transfer integral, induced by the perpetual molecular motion of organic materials owing to the combination of its molecular shape and its particular HOMO configuration. Notably, ChDT derivatives exhibit excellent chemical and thermal stability, high charge‐carrier mobility under ambient conditions (μ ≤ 10 cm2 V−1 s−1), and a crystal phase that is highly stable, even at temperatures above 250 °C. ","subitem_description_type":"Abstract"}]},"item_5_publisher_27":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"WILEY"}]},"item_5_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/advs.201700317","subitem_relation_type_select":"DOI"}}]},"item_5_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2017 The Authors. "},{"subitem_rights":"Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited."}]},"item_5_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_5_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"21983844","subitem_source_identifier_type":"ISSN"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yamamoto, Akito"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Murata, Yoshinori"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Mitsui, Chikahiko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ishii, Hiroyuki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yamagishi, Masakazu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yano, Masafumi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sato, Hiroyasu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yamano, Akihito"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Takeya, Jun"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Okamoto, Toshihiro"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-10-22"}],"displaytype":"detail","filename":"AS_5-1700317.pdf","filesize":[{"value":"2.1 MB"}],"format":"application/pdf","licensetype":"license_6","mimetype":"application/pdf","url":{"label":"AS_5-1700317","url":"https://tsukuba.repo.nii.ac.jp/record/47757/files/AS_5-1700317.pdf"},"version_id":"5c961994-9f41-4ac4-9064-cc4ae1663464"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Zigzag-Elongated Fused π-Electronic Core: A Molecular Design Strategy to Maximize Charge-Carrier Mobility","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Zigzag-Elongated Fused π-Electronic Core: A Molecular Design Strategy to Maximize Charge-Carrier Mobility"}]},"item_type_id":"5","owner":"1","path":["1448","7096"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-10-22"},"publish_date":"2018-10-22","publish_status":"0","recid":"47757","relation_version_is_last":true,"title":["Zigzag-Elongated Fused π-Electronic Core: A Molecular Design Strategy to Maximize Charge-Carrier Mobility"],"weko_creator_id":"1","weko_shared_id":5},"updated":"2022-04-27T09:19:51.719308+00:00"}