{"created":"2021-03-01T07:25:50.511397+00:00","id":45968,"links":{},"metadata":{"_buckets":{"deposit":"12150ff6-87d8-4e43-a653-4e1fee3c6e71"},"_deposit":{"id":"45968","owners":[],"pid":{"revision_id":0,"type":"depid","value":"45968"},"status":"published"},"_oai":{"id":"oai:tsukuba.repo.nii.ac.jp:00045968","sets":["117:1207","117:1706","117:2918","3:62:5296:5285"]},"item_5_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-12","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"7","bibliographicPageEnd":"1977","bibliographicPageStart":"1973","bibliographicVolumeNumber":"57","bibliographic_titles":[{"bibliographic_title":"Angewandte Chemie international edition"}]}]},"item_5_creator_3":{"attribute_name":"著者別名","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"小谷, 弘明"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"石塚, 智也"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"小島, 隆彦"}],"nameIdentifiers":[{},{},{}]}]},"item_5_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The two‐electron reduction of a diprotonated dodecaphenylporphyrin derivative by Na2S2O4 gave a corresponding isophlorin (Iph) selectively. Formation of Iph was confirmed by spectroscopic measurements and the isolation of tetramethylated Iph. Further reduction of Iph proceeded to form an unprecedented four‐electron‐reduced porphyrin (IphH2), which was fully characterized by spectroscopic and X‐ray crystallographic analysis. IphH2, with a unique conformation, could be oxidized to reproduce the starting porphyrin, resulting in a proton‐coupled four‐electron reversible redox system. ","subitem_description_type":"Abstract"}]},"item_5_publisher_27":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley"}]},"item_5_relation_10":{"attribute_name":"PubMed番号","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"29206356","subitem_relation_type_select":"PMID"}}]},"item_5_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/anie.201711058","subitem_relation_type_select":"DOI"}}]},"item_5_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2018 Wiley-VCH Verlag GmbH &Co. KGaA, Weinheim "},{"subitem_rights":"This is the pre-peer reviewed version of the following article: Angew. Chem. Int. Ed. 2017,57,1973-1977, which has been published in final form at 10.1002/anie.201711058. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."}]},"item_5_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_5_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1433-7851","subitem_source_identifier_type":"ISSN"}]},"item_5_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA0052535X","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Suzuki, Wataru"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kotani, Hiroaki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ishizuka, Tomoya"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Shiota, Yoshihito"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yoshizawa, Kazunari"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kojima, Takahiko"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-01-01"}],"displaytype":"detail","filename":"ACIE_57-7.pdf","filesize":[{"value":"4.9 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ACIE_57-7","url":"https://tsukuba.repo.nii.ac.jp/record/45968/files/ACIE_57-7.pdf"},"version_id":"50f6ba0f-23b1-4ddc-bb76-7c65eb291628"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Formation and Isolation of a Four-Electron-Reduced Porphyrin Derivative by Reduction of a Stable 20π Isophlorin","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Formation and Isolation of a Four-Electron-Reduced Porphyrin Derivative by Reduction of a Stable 20π Isophlorin"}]},"item_type_id":"5","owner":"1","path":["1706","1207","2918","5285"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-04-16"},"publish_date":"2018-04-16","publish_status":"0","recid":"45968","relation_version_is_last":true,"title":["Formation and Isolation of a Four-Electron-Reduced Porphyrin Derivative by Reduction of a Stable 20π Isophlorin"],"weko_creator_id":"1","weko_shared_id":5},"updated":"2022-04-27T09:17:44.989667+00:00"}