@article{oai:tsukuba.repo.nii.ac.jp:00045389, author = {藤田, 健志 and 市川, 淳士 and Fujita, Takeshi and Kinoshita, Ryo and Takanohashi, Tsuyoshi and Suzuki, Naoto and Ichikawa, Junji}, journal = {Beilstein Journal of Organic Chemistry}, month = {Dec}, note = {1,1-Difluoro-1-alkenes bearing a biaryl-2-yl group effectively underwent site-selective intramolecular iodoarylation by the appropriate cationic iodine species. Iodoarylation of 2-(2-aryl-3,3-difluoroallyl)biaryls proceeded via regioselective carbon–carbon bond formation at the carbon atoms in β-position to the fluorine substituents, thereby constructing dibenzo-fused six-membered carbocycles bearing a difluoroiodomethyl group. In contrast, 2-(3,3-difluoroallyl)biaryls underwent a similar cyclization at the α-carbon atoms to afford ring-difluorinated seven-membered carbocycles.}, pages = {2682--2689}, title = {Ring-size-selective construction of fluorine-containing carbocycles via intramolecular iodoarylation of 1,1-difluoro-1-alkenes}, volume = {13}, year = {2017} }