{"created":"2021-03-01T07:22:06.915349+00:00","id":42594,"links":{},"metadata":{"_buckets":{"deposit":"20a02a20-c8ea-4b22-9326-61f477b779be"},"_deposit":{"id":"42594","owners":[],"pid":{"revision_id":0,"type":"depid","value":"42594"},"status":"published"},"_oai":{"id":"oai:tsukuba.repo.nii.ac.jp:00042594","sets":["117:1221","117:500","3:62:5592:420"]},"item_5_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-09","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"195","bibliographicPageStart":"189","bibliographicVolumeNumber":"845","bibliographic_titles":[{"bibliographic_title":"Journal of organometallic chemistry"}]}]},"item_5_creator_3":{"attribute_name":"著者別名","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"桑原, 純平"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"神原, 貴樹"}],"nameIdentifiers":[{},{},{}]}]},"item_5_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Ir complexes bearing pincer ligands are expected to be efficient phosphorescent materials. This work investigated the solid-state structures and photophysical properties of Ir(III) complexes that contain different NCN pincer ligands (NCN = 1,3-bis(2-benzothiazolyl)benzene, 1,3-bis(2-benzoxazoyl)benzene, or 1,3-bis(2-benzimidazoyl)benzene derivatives), bidentate cyclometalating NC ligands (NC = 2-phenylpyridine or 2-phenylbenzothiazole), and anionic ancillary ligands. The structure of the NCN pincer ligands is a dominant factor for determining the emission wavelength, rather than the bidentate NC and ancillary ligands. The organic light emitting diodes (OLEDs) with an Ir(III) complex show electroluminescence with 14% external quantum efficiency at 1 mAcm−2. Modification of the device structure improved the efficiency at the high current density region.","subitem_description_type":"Abstract"}]},"item_5_publisher_27":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier "}]},"item_5_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.jorganchem.2017.04.037","subitem_relation_type_select":"DOI"}}]},"item_5_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2017. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ "}]},"item_5_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_5_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0022-328X","subitem_source_identifier_type":"ISSN"}]},"item_5_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00704122 ","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kuwabara, Junpei"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Namekawa, Tomomi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sakabe, Eiko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Haga, Masa-aki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"神原, 貴樹"},{"creatorName":"カンバラ, タカキ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-10-01"}],"displaytype":"detail","filename":"JOC_845.pdf","filesize":[{"value":"963.4 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"JOC_845","url":"https://tsukuba.repo.nii.ac.jp/record/42594/files/JOC_845.pdf"},"version_id":"2766cfc6-3cc4-488d-8e66-5a603fd17b84"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Luminescent Ir(III) complexes bearing benzothiazole or benzoxazole-based pincer ligand","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Luminescent Ir(III) complexes bearing benzothiazole or benzoxazole-based pincer ligand"}]},"item_type_id":"5","owner":"1","path":["500","1221","420"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-09-12"},"publish_date":"2017-09-12","publish_status":"0","recid":"42594","relation_version_is_last":true,"title":["Luminescent Ir(III) complexes bearing benzothiazole or benzoxazole-based pincer ligand"],"weko_creator_id":"1","weko_shared_id":5},"updated":"2022-04-27T09:13:43.604494+00:00"}