{"created":"2021-03-01T07:19:45.036858+00:00","id":40376,"links":{},"metadata":{"_buckets":{"deposit":"058810d1-5ea1-4ecf-9c42-4c82cdc82ae0"},"_deposit":{"id":"40376","owners":[],"pid":{"revision_id":0,"type":"depid","value":"40376"},"status":"published"},"_oai":{"id":"oai:tsukuba.repo.nii.ac.jp:00040376","sets":["117:300","117:488","117:5717","3:62:5596:2060"]},"item_5_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1277","bibliographicVolumeNumber":"11","bibliographic_titles":[{"bibliographic_title":"Nanoscale Research Letters"}]}]},"item_5_creator_3":{"attribute_name":"著者別名","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"近藤, 剛弘"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"中村, 潤児"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"丹羽, 秀治"}],"nameIdentifiers":[{},{},{}]}]},"item_5_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The characteristics of CO2 adsorption sites on a nitrogen-doped graphite model system (N-HOPG) were investigated by X-ray photoelectron and absorption spectroscopy and infrared reflection absorption spectroscopy. Adsorbed CO2 was observed lying flat on N-HOPG, stabilized by a charge transfer from the substrate. This demonstrated that Lewis base sites were formed by the incorporation of nitrogen via low-energy nitrogen-ion sputtering. The possible roles of twofold coordinated pyridinic N and threefold coordinated valley N (graphitic N) sites in Lewis base site formation on N-HOPG are discussed. The presence of these nitrogen species focused on the appropriate interaction strength of CO2 indicates the potential to fine-tune the Lewis basicity of carbon-based catalysts.","subitem_description_type":"Abstract"}]},"item_5_publisher_27":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":" Springer  "}]},"item_5_relation_10":{"attribute_name":"PubMed番号","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":" 26951127","subitem_relation_type_select":"PMID"}}]},"item_5_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1186/s11671-016-1344-6","subitem_relation_type_select":"DOI"}}]},"item_5_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2016 Kiuchi et al."},{"subitem_rights":"Open Access This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made"}]},"item_5_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_5_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1931-7573","subitem_source_identifier_type":"ISSN"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kiuchi, Hisao"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Shibuya, Riku"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kondo, Takahiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nakamura, Junji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Niwa, Hideharu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Miyawaki, Jun"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kawai, Maki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Oshima, Masaharu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Harada, Yoshihisa"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-02-28"}],"displaytype":"detail","filename":"NRL_11-127.pdf","filesize":[{"value":"1.5 MB"}],"format":"application/pdf","licensetype":"license_6","mimetype":"application/pdf","url":{"label":"NRL_11-127","url":"https://tsukuba.repo.nii.ac.jp/record/40376/files/NRL_11-127.pdf"},"version_id":"63410e0d-61a9-4447-a1ea-e396d869d318"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Lewis Basicity of Nitrogen-Doped Graphite Observed by CO2 Chemisorption","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Lewis Basicity of Nitrogen-Doped Graphite Observed by CO2 Chemisorption"}]},"item_type_id":"5","owner":"1","path":["300","488","5717","2060"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-02-28"},"publish_date":"2017-02-28","publish_status":"0","recid":"40376","relation_version_is_last":true,"title":["Lewis Basicity of Nitrogen-Doped Graphite Observed by CO2 Chemisorption"],"weko_creator_id":"1","weko_shared_id":5},"updated":"2022-04-27T09:10:46.029685+00:00"}