@article{oai:tsukuba.repo.nii.ac.jp:00037581,
 author = {小島, 誠治 and Ahart, Muhtar and Somayazulu, Maddury and Kojima, Seiji and Yasuda, Naohiko and Prosandeev, Sergey and Hemley, Russell J.},
 issue = {04},
 journal = {Journal of Advanced Dielectrics},
 month = {Dec},
 note = {Room-temperature Raman scattering and x-ray diffraction measurements together with first-principles calculations were employed
to investigate the behavior of disordered Pb(In1=2Nb1=2ÞO3 (PIN) under pressure up to 50 GPa. Raman spectra show broad bands but
a peak near the 380 cm−1 increases its intensity with pressure. The linewidth of the band at 550 cm−1 also increases with pressure,
while two of the Raman peaks merge above 6 GPa. Above 16 GPa, we observe additional splitting of the band at 50 cm−1. The
pressure evolution of the diffraction patterns for PIN shows obvious Bragg peaks splitting above 16 GPa; consistent with a
symmetry lowering transition. The transition at 0.5 GPa is identified as a pseudo-cubic to orthorhombic (Pbam) structural change
whereas the transition at 16 GPa is isostructure and associated with changes in linear compressibility and octahedral titling, and the
transition at 30 GPa is associated to an orthorhombic to monoclinic change. First-principles calculations indicate that the Pbam
structure is ground state with antiferrodisdortion consistent with experiment.},
 title = {Structural transitions in Pb(In1∕2 Nb1∕2 )O3 under pressure},
 volume = {05},
 year = {2015}
}