@article{oai:tsukuba.repo.nii.ac.jp:00033774, author = {沓村, 憲樹 and Kutsumura, Noriki and Matsubara, Yusuke and Honjo, Takuya and Ohgiya, Tadaaki and Nishiyama, Shigeru and Saito, Takao}, issue = {16}, journal = {Tetrahedron}, month = {Apr}, note = {The first total synthesis of (−)-5,6-seco-germacrane lactone has been achieved. The synthetic highlight of our approach includes sp2–sp3 Suzuki–Miyaura cross coupling of a vinyl bromide and an alkyl 9-BBN derivative. The vinyl bromide was easily prepared from the chiral lactonic building block using a one-pot regioselective bromination. The asymmetric carbon center of the alkyl boron compound was formed using the zirconium-catalyzed carbomagnesation of 2,5-dihydrofuran.}, pages = {2382--2386}, title = {Total synthesis of (−)-5,6-seco-germacrane lactone}, volume = {71}, year = {2015} }