{"created":"2021-03-01T07:08:01.174703+00:00","id":29523,"links":{},"metadata":{"_buckets":{"deposit":"2a151bd3-c886-400f-9086-eae01e0beb74"},"_deposit":{"id":"29523","owners":[],"pid":{"revision_id":0,"type":"depid","value":"29523"},"status":"published"},"_oai":{"id":"oai:tsukuba.repo.nii.ac.jp:00029523","sets":["117:496","3:62:5598:659"]},"item_5_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"72","bibliographicPageStart":"66","bibliographicVolumeNumber":"55","bibliographic_titles":[{"bibliographic_title":"Polymer"}]}]},"item_5_creator_3":{"attribute_name":"著者別名","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"後藤, 博正"}],"nameIdentifiers":[{},{},{}]}]},"item_5_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A series of optically inactive aryl isocyanide derivatives were polymerized with an achiral nickel catalyst (Ni(II)Cl2) in a cholesteric liquid crystal (CLC) medium. The polymers synthesized from ortho-substituted phenyl isocyanide monomers in CLC phase show optical activity even though they have no chiral carbons. The Cotton effects of these polymers suggest that main chains of the polymers formed predominantly one-handed helical conformation. One-handed chiral environment in reaction state provided by CLC medium allows the formation of the polymers. The helical sense of the polymers is controllable by choice of (R)- or (S)-CLC as reaction solvent, though the monomer is same.","subitem_description_type":"Abstract"}]},"item_5_identifier_34":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2241/120959"}]},"item_5_publisher_27":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier Ltd."}]},"item_5_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.polymer.2013.12.009","subitem_relation_type_select":"DOI"}}]},"item_5_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2013 Elsevier Ltd."},{"subitem_rights":"NOTICE: this is the author’s version of a work that was accepted for publication in Polymer. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Polymer,55,1,2014.http://dx.doi.org/10.1016/j.polymer.2013.12.009"}]},"item_5_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_5_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0032-3861","subitem_source_identifier_type":"ISSN"}]},"item_5_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00776983","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Iseki, Tomokazu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kawabata, Kohsuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kawashima, Hirotsugu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Goto, Hiromasa"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2014-05-09"}],"displaytype":"detail","filename":"POLYMER_55-1.pdf","filesize":[{"value":"1.6 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"POLYMER_55-1.pdf","url":"https://tsukuba.repo.nii.ac.jp/record/29523/files/POLYMER_55-1.pdf"},"version_id":"469e3381-4fbe-4b03-a7ea-272411e470d8"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Catalysis direction selective asymmetric polymerization in chiral liquid crystal medium","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Catalysis direction selective asymmetric polymerization in chiral liquid crystal medium"}]},"item_type_id":"5","owner":"1","path":["496","659"],"pubdate":{"attribute_name":"公開日","attribute_value":"2014-03-12"},"publish_date":"2014-03-12","publish_status":"0","recid":"29523","relation_version_is_last":true,"title":["Catalysis direction selective asymmetric polymerization in chiral liquid crystal medium"],"weko_creator_id":"1","weko_shared_id":5},"updated":"2022-04-27T08:58:03.943244+00:00"}