{"created":"2021-03-01T07:05:30.388059+00:00","id":27220,"links":{},"metadata":{"_buckets":{"deposit":"b2a4bbfb-ecc5-4a1d-9a5d-0eaea20bc915"},"_deposit":{"id":"27220","owners":[],"pid":{"revision_id":0,"type":"depid","value":"27220"},"status":"published"},"_oai":{"id":"oai:tsukuba.repo.nii.ac.jp:00027220","sets":["117:487","3:62:5592:1088"]},"item_5_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2012-06","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"149","bibliographicPageStart":"141","bibliographicVolumeNumber":"207","bibliographic_titles":[{"bibliographic_title":"Journal of power sources"}]}]},"item_5_creator_3":{"attribute_name":"著者別名","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"市川, 淳士"}],"nameIdentifiers":[{},{},{}]}]},"item_5_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Five 1,1-difluoro-1-alkenes bearing aryl groups are investigated as electrolyteadditives for high-charge-voltage lithiumionbatteries with an aim to induce favorable solid electrolyte interphase (SEI) formation. Among them, 1,1-difluoro-4-phenylbut-1-ene (DF-1) forms appropriate SEIs on the cathode and anode by its reactions under oxidative and reductive conditions, respectively, which was suggested by linear sweep and cyclic voltammetry. The SEIs formed with the DF-1 containing electrolyte on the cathode and anode were analyzed by X-ray photoelectron spectroscopy and time of flight-secondary ion mass spectrometry, indicating the following: (i) the cathode surface has a LiF-rich layer with unsaturated hydrocarbons, and (ii) the anode surface also has a LiF-rich layer, which probably includes fluoromethylene (CHF) compounds. The formation of the SEIs on both electrodes with DF-1 results in low impedance being maintained, and thus, particularly good cycle performance even at high-charge-voltage.","subitem_description_type":"Abstract"}]},"item_5_identifier_34":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2241/117044"}]},"item_5_publisher_27":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier B.V."}]},"item_5_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.jpowsour.2012.01.139","subitem_relation_type_select":"DOI"}}]},"item_5_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2012 Elsevier B.V.　NOTICE: this is the author’s version of a work that was accepted for publication in Journal of power sources. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in PUBLICATION, VOL207 , 2012, DOI:10.1016/j.jpowsour.2012.01.139"}]},"item_5_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_5_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0378-7753","subitem_source_identifier_type":"ISSN"}]},"item_5_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00705373","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kubota, Tadahiko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ihara, Masayuki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Katayama, Shinichi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nakai, Hideki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ichikawa, Junji"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2013-12-25"}],"displaytype":"detail","filename":"JPS_207.pdf","filesize":[{"value":"1.7 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JPS_207.pdf","url":"https://tsukuba.repo.nii.ac.jp/record/27220/files/JPS_207.pdf"},"version_id":"a4292a8a-ed4c-4cce-9768-2ce187f93bbb"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"1,1-Difluoro-1-alkenes as New Electrolyte Additives for Lithium Ion Batteries","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"1,1-Difluoro-1-alkenes as New Electrolyte Additives for Lithium Ion Batteries"}]},"item_type_id":"5","owner":"1","path":["487","1088"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-05-23"},"publish_date":"2012-05-23","publish_status":"0","recid":"27220","relation_version_is_last":true,"title":["1,1-Difluoro-1-alkenes as New Electrolyte Additives for Lithium Ion Batteries"],"weko_creator_id":"1","weko_shared_id":5},"updated":"2022-04-27T08:55:04.196413+00:00"}