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Cyanide bridged tetranuclear complex with a novel terthiophene based ligand
http://hdl.handle.net/2241/115783
http://hdl.handle.net/2241/115783852104a1-3fb6-40f6-8309-202f20405a5c
名前 / ファイル | ライセンス | アクション |
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PH_30-18.pdf (668.0 kB)
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Item type | Journal Article(1) | |||||
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公開日 | 2012-03-08 | |||||
タイトル | ||||||
タイトル | Cyanide bridged tetranuclear complex with a novel terthiophene based ligand | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Mitsumoto, Kiyotaka
× Mitsumoto, Kiyotaka× Nishikawa, Hiroyuki× Oshio, Hiroki |
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著者別名 |
大塩, 寛紀
× 大塩, 寛紀 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A new terthiophene based ligand (L = 3-(2-pryridyl)-5-(2,2′:5′,2″-terthien-3′-yl) pyrazole was synthesized. The reaction of Ni(BF4)2·6H2O, L and nBu4N[Fe(CN)3tp∗] (tp∗ = tris(3,5-dimethylpyrazol-1-yl)borohyrdide) with NaBPh4 in MeOH/acetone yielded a cyanide bridged tetranuclear complex [Fe2Ni2(CN)6(tp∗)2(L)4](BPh4)2 (1). The electrochemical properties of both 1 and L were investigated, and magnetic susceptibility measurements of 1 were conducted, revealing that ferromagnetic interactions were operative within the tetranuclear core. | |||||
書誌情報 |
Polyhedron 巻 30, 号 18, p. 3245-3248, 発行日 2011-11 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0277-5387 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA10531370 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1016/j.poly.2011.04.035 | |||||
権利 | ||||||
権利情報 | © 2011 Elsevier Ltd. NOTICE: this is the author’s version of a work that was accepted for publication in Polyhedron. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in PUBLICATION, VOL30, ISSUE18, 2011 DOI:10.1016/j.poly.2011.04.035 | |||||
著者版フラグ | ||||||
値 | author | |||||
出版者 | ||||||
出版者 | Elsevier Ltd. | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2241/115783 | |||||
識別子タイプ | HDL |