{"created":"2021-10-04T01:33:26.861746+00:00","id":2001502,"links":{},"metadata":{"_buckets":{"deposit":"af575b32-ba7f-4884-891f-01a863241401"},"_deposit":{"created_by":25,"id":"2001502","owner":"25","owners":[25],"owners_ext":{"displayname":"wataka","username":"kuma1008"},"pid":{"revision_id":0,"type":"depid","value":"2001502"},"status":"published"},"_oai":{"id":"oai:tsukuba.repo.nii.ac.jp:02001502","sets":["117:2136","117:4917","117:8165","3:62:5298:1633310956209"]},"author_link":["204972","140587","744"],"control_number":"2001502","item_5_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-08","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageStart":"118","bibliographicVolumeNumber":"3","bibliographic_titles":[{"bibliographic_title":"Communications Chemistry","bibliographic_titleLang":"en"}]}]},"item_5_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Vapochromic behaviour of porous crystals is beneficial for facile and rapid detection of gaseous molecules without electricity. Toward this end, tailored molecular designs have been established for metal–organic, covalent-bonded and hydrogen-bonded frameworks. Here, we explore the hydrochromic chemistry of a van der Waals (VDW) porous crystal. The VDW porous crystal VPC-1 is formed from a novel aromatic dendrimer having a dibenzophenazine core and multibranched carbazole dendrons. Although the constituent molecules are connected via VDW forces, VPC-1 maintains its structural integrity even after desolvation. VPC-1 exhibits reversible colour changes upon uptake/release of water molecules due to the charge transfer character of the constituent dendrimer. Detailed structural analyses reveal that the outermost carbazole units alone are mobile in the crystal and twist simultaneously in response to water vapour. Thermodynamic analysis suggests that the sigmoidal water sorption is induced by the affinity alternation of the pore surface from hydrophobic to hydrophilic.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_5_publisher_27":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Nature","subitem_publisher_language":"en"}]},"item_5_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1038/s42004-020-00364-3","subitem_relation_type_select":"DOI"}}]},"item_5_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© The Author(s) 2020  This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.","subitem_rights_language":"en"}]},"item_5_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_5_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2399-3669","subitem_source_identifier_type":"EISSN"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"山岸, 洋","creatorNameLang":"ja"},{"creatorName":"ヤマギシ, ヒロシ","creatorNameLang":"ja-Kana"},{"creatorName":"YAMAGISHI, Hiroshi","creatorNameLang":"en"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Nakajima, Sae","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Yoo, Jooyoung","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Okazaki, Masato","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Takeda, Youhei","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Minakata, Satoshi","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Albrecht, Ken","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Yamamoto, Kimihisa","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Badía-Domínguez, Irene","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Oliva, Maria Moreno","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Delgado, M. Carmen Ruiz","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Ikemoto, Yuka","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Sato, Hiroyasu","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Imoto, Kenta","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Nakagawa, Kosuke","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"所, 裕子","creatorNameLang":"ja"},{"creatorName":"トコロ, ヒロコ","creatorNameLang":"ja-Kana"},{"creatorName":"TOKORO, Hiroko","creatorNameLang":"en"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Ohkoshi, Shin-ichi","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"山本, 洋平","creatorNameLang":"ja"},{"creatorName":"ヤマモト, ヨウヘイ","creatorNameLang":"ja-Kana"},{"creatorName":"YAMAMOTO, Yohei","creatorNameLang":"en"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2021-10-04"}],"displaytype":"detail","filename":"CC_3-118.pdf","filesize":[{"value":"2.2 MB"}],"format":"application/pdf","licensetype":"license_0","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://tsukuba.repo.nii.ac.jp/record/2001502/files/CC_3-118.pdf"},"version_id":"39d9e72c-0d72-4aa7-bbf4-19789714e0df"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Sigmoidally hydrochromic molecular porous crystal with rotatable dendrons","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Sigmoidally hydrochromic molecular porous crystal with rotatable dendrons","subitem_title_language":"en"}]},"item_type_id":"5","owner":"25","path":["4917","8165","2136","1633310956209"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2021-10-04"},"publish_date":"2021-10-04","publish_status":"0","recid":"2001502","relation_version_is_last":true,"title":["Sigmoidally hydrochromic molecular porous crystal with rotatable dendrons"],"weko_creator_id":"25","weko_shared_id":-1},"updated":"2022-04-27T10:55:45.779222+00:00"}