2024-03-28T17:15:55Z
https://tsukuba.repo.nii.ac.jp/oai
oai:tsukuba.repo.nii.ac.jp:00053651
2022-04-27T09:27:38Z
117:1707
3:62:5598:1879
Disilyne with a silicon-silicon triple bond: A new entry to multiple bond chemistry
関口, 章
セキグチ, アキラ
SEKIGUCHI, Akira
The synthesis, crystal structure, and characterization of a silicon-silicon triply bonded species, disilyne with two bis[bis(trimethylsilyl)methyl]isopropylsilyl substituents, are described. The nature of the sp-hybridized silicon atoms is discussed from the viewpoint of spectroscopic results and theoretical calculations. The reactivity of the disilyne with alkali metals, tBuLi, and π-bonded compounds such as cis- and trans-2-butenes and phenylacetylene is also described.
International Symposium on Novel Aromatic Compounds (ISNA-12), International Symposium on Novel Aromatic Compounds, ISNA, Novel Aromatic Compounds, 12th, Awaji Island, Japan, 2007-07-22–2007-07-27
journal article
International Union of Pure and Applied Chemistry
2008-03
application/pdf
Pure and Applied Chemistry
3
80
447
457
0033-4545
AA00797859
https://tsukuba.repo.nii.ac.jp/record/53651/files/PAC_80-3.pdf
eng
10.1351/pac200880030447
© 2008 IUPAC