2024-03-28T12:08:20Z
https://tsukuba.repo.nii.ac.jp/oai
oai:tsukuba.repo.nii.ac.jp:00048141
2022-04-27T09:20:17Z
117:498
3:62:5298:7105
Site-Selective Hydrosilylation of Botryococcene - The Algal Biomass Hydrocarbon Oil
川島, 英久
木島, 正志
Kawashima, Hidehisa
Umezawa, Mami
Kijima, Masashi
A biomass oil, botryococcene ((E)‐2,3,7,10,13,16,20,21‐octamethyl‐6,17‐dimethylene‐10‐vinyldocosa‐1,11,21‐triene), produced from microalga “Botryococcus braunii” was epoxidized by Prilezaev reaction using excess amount of m‐chloroperoxybenzoic acid under mild conditions for the purpose of applicative derivatizations of the oil. The oil underwent epoxidations at the C2,6,17,21‐positioned four vinylidenes and C11‐12 vinylene site‐selectively except the electronically inactive C10‐vinyl, giving the botryococcene pentaepoxide in high yield.
journal article
wiley
2018-01
application/pdf
application/pdf
ChemistrySelect
1
3
273
276
23656549
https://tsukuba.repo.nii.ac.jp/record/48141/files/CS_3-1.pdf
https://tsukuba.repo.nii.ac.jp/record/48141/files/CS_3-1-information.pdf
eng
10.1002/slct.201702686
©2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim