2024-03-29T04:57:25Z
https://tsukuba.repo.nii.ac.jp/oai
oai:tsukuba.repo.nii.ac.jp:00037509
2023-02-01T03:09:48Z
117:3195
117:3196
3:62:5296:5023
Crystal structure of the one-dimensional metal–organic polymer catena-poly[[tris(μ-2,4,6-trimethylbenzoato-κ2O:O′)-dizinc]-μ-2,4,6-trimethylbenzoato-κ2O:O′]
Yamamura, Masaki
山村, 正樹
鍋島, 達弥
ナベシマ, タツヤ
NABESHIMA, Tatsuya
open access
http://creativecommons.org/licenses/by/2.0/uk/legalcode
The title complex, [Zn2(C10H11O2)4]n, has a one-dimensional polymeric structure. The asymmetric unit consists of two zinc atoms bridged by three 2,4,6-trimethylbenzoate anions and one bidentate bridging 2,4,6-trimethylbenzoate anion. The [Zn2(C9H11CO2)3] cluster units are intermolecularly linked to form a one-dimensional polymer, which propagates in the direction of the crystallographic b axis. The Zn atoms adopt a tetrahedral geometry. The Zn—O bond lengths in the intramolecular bridges are slightly shorter than those in the intermolecular bridges.
International Union of Crystallography
2016-01
eng
journal article
VoR
http://hdl.handle.net/2241/00137692
https://tsukuba.repo.nii.ac.jp/records/37509
https://doi.org/10.1107/S2056989014027418
2056-9890
Acta Crystallographica Section E, Crystallographic communications
71
1
m14
m15
https://tsukuba.repo.nii.ac.jp/record/37509/files/ActaCE_71-1.pdf
application/pdf
396.1 kB
2016-03-25