2024-03-28T10:39:11Z
https://tsukuba.repo.nii.ac.jp/oai
oai:tsukuba.repo.nii.ac.jp:00035762
2022-04-27T09:48:22Z
117:496
3:62:5586:2545
Synthesis and optical properties of poly(phenylenethiophene)s bearing conjugated side chains
後藤, 博正
Kawashima, Hirotsugu
Kawabata, Kohsuke
Wang, Aohan
Goto, Hiromasa
This is an Accepted Manuscript of an article published by Taylor & Francis in Designed monomers and polymers on 05 Aug 2015 available online: http://www.tandfonline.com/10.1080/15685551.2015.1070498.
A series of π-conjugated polymers bearing conjugated side chain were prepared by Migita–Kosugi–Stille coupling polycondensation reaction. The polymers consisting of phenylene–thiophene (CCPTO), phenylene–isothianaphthene (CCPIO), and phenylene-3,4-ethylenedioxythiophene (CCPEO) conjugated backbones in the main chains showed optical absorption peaks in the same region, while fluorescence peak of CCPTO was at larger wavelengths compared with those of CCPIO and CCPEO. The polymers showed optical rotary dispersion, indicating the optically active substituents induced one-handed helicity to the polymers.
Taylor and Francis Group
2015-10
eng
journal article
http://hdl.handle.net/2241/00128910
https://tsukuba.repo.nii.ac.jp/records/35762
10.1080/15685551.2015.1070498
1385-772X
1568-5551
AA11640462
Designed monomers and polymers
18
7
661
668
https://tsukuba.repo.nii.ac.jp/record/35762/files/DMP_18-7.pdf
application/pdf
1.2 MB
2016-11-01