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2023-05-02T01:13:30Z
3:233:254
Triplet sensitization mechanisms and intermediates in photodecomposition of diaroyl peroxides
高原, 茂
Takahara, Shigeru
open access
The purposes of this investigation are concentrated at two points from the viewpoint of wide stages of photochemistry. One is to elucidate the mechanisms of photochemical bond cleavage and to clarity the differences among the modes of direct and sensitized photolyses, and thermolyses. The other is to clarity behavior of radicals in solution under or by photoirradiation.
Diaroyl peroxides are decomposed thermally 1-5) and photochemically, 6-13, 15-29) and used as radical initiator. The diaroyl peroxides, which have π-electronic systems as chromophores, also known to be decomposed by singlet 26-28, 30) and triplet sensitization. 21-25, 27, 29) It has been claritied that there are some processes leading to he decomposition of diaroyl peroxides ・・・
1984
1985
jpn
doctoral thesis
http://hdl.handle.net/2241/6837
https://tsukuba.repo.nii.ac.jp/records/8365
https://www.tulips.tsukuba.ac.jp/opac/volume/546172
本文はOPACにあり
甲第291号
博士(理学)
Doctor of Philosophy in Science
1985-03-25
12102
筑波大学
University of Tsukuba
https://tsukuba.repo.nii.ac.jp/record/8365/files/A0291.pdf
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2013-12-18