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Polarons radical polymerization
http://hdl.handle.net/2241/00153399
http://hdl.handle.net/2241/00153399b14e8920-7f84-46d8-a2db-a7c73a888e25
名前 / ファイル | ライセンス | アクション |
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JPSA_56-7 (1.1 MB)
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Item type | Journal Article(1) | |||||
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公開日 | 2018-10-02 | |||||
タイトル | ||||||
タイトル | Polarons radical polymerization | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Yamabe, Kohei
× Yamabe, Kohei× Nakajima, Kuniharu× Goto, Hiromasa |
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著者別名 |
後藤, 博正
× 後藤, 博正 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Polystyrene has been typically prepared with radical polymerization by benzoyl peroxide (BPO) or azobisisobutyronitrile (AIBN). In this report, polymerization of styrene was carried out by radical cations of polyaniline (PANI). Polarons of conducting polymers are consisting of radical cations. The polarons bear electrical conduction as a charge carrier. We employ the polarons as an initiator for radical polymerization. Polymerization of styrene and acrylonitrile by the polarons was conducted to explore new possibility of conducting polymers. Fourier‐transfer infrared absorption (FTIR) spectroscopy measurements for the resultant polymers obtained with polarons of polyaniline indicates that the polystyrene thus synthesized grows from polyaniline. The qualitative solubility, average molecular weight, and thermal stability are comparable to that of polystyrene obtained by the common method with BPO. Radical polymerization by polarons may provide a new avenue for radical polymerizations through application of conducting polymer. | |||||
書誌情報 |
Journal of polymer science. Part A, Polymer chemistry 巻 56, 号 7, p. 805-811, 発行日 2018-04 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0887624X | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA1068915X | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1002/pola.28956 | |||||
権利 | ||||||
権利情報 | © 2017 Wiley Periodicals, Inc. This is the peer reviewed version of the following article: Journal of polymer science. Part A, Polymer chemistry, which has been published in final form at DOI:10.1002/pola.28956. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | |||||
著者版フラグ | ||||||
値 | author | |||||
出版者 | ||||||
出版者 | Wiley |