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Twofold fused concave hosts containing two phosphorus atoms: modules for the sandwich-type encapsulation of fullerenes in variable cavities
http://hdl.handle.net/2241/00131154
http://hdl.handle.net/2241/001311545946051b-df0c-47ad-bb01-b9a0c6cc94cf
名前 / ファイル | ライセンス | アクション |
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CS_6-11 (2.0 MB)
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Item type | Journal Article(1) | |||||
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公開日 | 2015-12-08 | |||||
タイトル | ||||||
タイトル | Twofold fused concave hosts containing two phosphorus atoms: modules for the sandwich-type encapsulation of fullerenes in variable cavities | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Yamamura, Masaki
× Yamamura, Masaki× Hongo, Daigo× Nabeshima, Tatsuya |
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著者別名 |
山村, 正樹
× 山村, 正樹× 鍋島, 達弥 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The design and synthesis of extended concave host P2 by fusion of two concave phosphorus-containing units is reported. Co-crystallization of P2 and the fullerene guests C60 and C70 afforded the 2 : 1 host–guest complexes (P2)2 ⊃ C60 and (P2)2 ⊃ C70, in which the two concave surfaces of P2 encapsulate the convex surface of the fullerenes in a sandwich fashion. Interestingly, the orientation of the two P2 molecules with respect to each other was observed to be flexible, resulting in the formation of a variety of cavity shapes. MALDI-TOF mass, NMR, and UV-vis absorption spectra supported the formation of host–guest complexes between P2 and the fullerenes in solution. The affinity of P2, containing two phosphorus atoms, towards fullerenes was significantly enhanced relative to P1 with one phosphorus atom. | |||||
書誌情報 |
Chemical science 巻 6, 号 11, p. 6373-6378, 発行日 2015-11 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 2041-6520 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA12555653 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1039/C5SC02224J | |||||
権利 | ||||||
権利情報 | © The Royal Society of Chemistry 2015. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. | |||||
著者版フラグ | ||||||
値 | publisher | |||||
出版者 | ||||||
出版者 | The Royal Society of Chemistry |