WEKO3
アイテム
{"_buckets": {"deposit": "38c279f0-ee6a-4b4f-9de9-5893801e6e2b"}, "_deposit": {"id": "53651", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "53651"}, "status": "published"}, "_oai": {"id": "oai:tsukuba.repo.nii.ac.jp:00053651", "sets": ["1707", "1879"]}, "item_5_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2008-03", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "3", "bibliographicPageEnd": "457", "bibliographicPageStart": "447", "bibliographicVolumeNumber": "80", "bibliographic_titles": [{}, {"bibliographic_title": "Pure and Applied Chemistry", "bibliographic_titleLang": "en"}]}]}, "item_5_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The synthesis, crystal structure, and characterization of a silicon-silicon triply bonded species, disilyne with two bis[bis(trimethylsilyl)methyl]isopropylsilyl substituents, are described. The nature of the sp-hybridized silicon atoms is discussed from the viewpoint of spectroscopic results and theoretical calculations. The reactivity of the disilyne with alkali metals, tBuLi, and π-bonded compounds such as cis- and trans-2-butenes and phenylacetylene is also described.", "subitem_description_type": "Abstract"}]}, "item_5_description_5": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "International Symposium on Novel Aromatic Compounds (ISNA-12), International Symposium on Novel Aromatic Compounds, ISNA, Novel Aromatic Compounds, 12th, Awaji Island, Japan, 2007-07-22–2007-07-27", "subitem_description_type": "Other"}]}, "item_5_publisher_27": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "International Union of Pure and Applied Chemistry"}]}, "item_5_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1351/pac200880030447", "subitem_relation_type_select": "DOI"}}]}, "item_5_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "© 2008 IUPAC"}]}, "item_5_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_5_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0033-4545", "subitem_source_identifier_type": "ISSN"}]}, "item_5_source_id_9": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00797859", "subitem_source_identifier_type": "NCID"}]}, "item_5_subject_20": {"attribute_name": "NIIサブジェクト", "attribute_value_mlt": [{"subitem_subject": "化学", "subitem_subject_scheme": "Other"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "関口, 章"}, {"creatorName": "セキグチ, アキラ", "creatorNameLang": "ja-Kana"}, {"creatorName": "SEKIGUCHI, Akira", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "134", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "90143164", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://nrid.nii.ac.jp/ja/nrid/1000090143164"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-12-03"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "PAC_80-3.pdf", "filesize": [{"value": "579.4 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 579400.0, "url": {"label": "PAC_80-3", "url": "https://tsukuba.repo.nii.ac.jp/record/53651/files/PAC_80-3.pdf"}, "version_id": "62754d7f-469c-45b6-ad4d-b5826f2ef41f"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Disilyne with a silicon-silicon triple bond: A new entry to multiple bond chemistry", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Disilyne with a silicon-silicon triple bond: A new entry to multiple bond chemistry", "subitem_title_language": "en"}]}, "item_type_id": "5", "owner": "1", "path": ["1707", "1879"], "permalink_uri": "http://hdl.handle.net/2241/00159069", "pubdate": {"attribute_name": "公開日", "attribute_value": "2019-12-03"}, "publish_date": "2019-12-03", "publish_status": "0", "recid": "53651", "relation": {}, "relation_version_is_last": true, "title": ["Disilyne with a silicon-silicon triple bond: A new entry to multiple bond chemistry"], "weko_shared_id": 5}
Disilyne with a silicon-silicon triple bond: A new entry to multiple bond chemistry
http://hdl.handle.net/2241/00159069
http://hdl.handle.net/2241/00159069c5491b45-3f74-4379-afb0-ad944fbefc99
名前 / ファイル | ライセンス | アクション |
---|---|---|
PAC_80-3 (579.4 kB)
|
|
Item type | Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2019-12-03 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Disilyne with a silicon-silicon triple bond: A new entry to multiple bond chemistry | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
関口, 章
× 関口, 章 |
|||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The synthesis, crystal structure, and characterization of a silicon-silicon triply bonded species, disilyne with two bis[bis(trimethylsilyl)methyl]isopropylsilyl substituents, are described. The nature of the sp-hybridized silicon atoms is discussed from the viewpoint of spectroscopic results and theoretical calculations. The reactivity of the disilyne with alkali metals, tBuLi, and π-bonded compounds such as cis- and trans-2-butenes and phenylacetylene is also described. | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | International Symposium on Novel Aromatic Compounds (ISNA-12), International Symposium on Novel Aromatic Compounds, ISNA, Novel Aromatic Compounds, 12th, Awaji Island, Japan, 2007-07-22–2007-07-27 | |||||
書誌情報 |
en : Pure and Applied Chemistry 巻 80, 号 3, p. 447-457, 発行日 2008-03 |
|||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0033-4545 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00797859 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1351/pac200880030447 | |||||
権利 | ||||||
権利情報 | © 2008 IUPAC | |||||
著者版フラグ | ||||||
値 | publisher | |||||
出版者 | ||||||
出版者 | International Union of Pure and Applied Chemistry |