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Site-Selective Hydrosilylation of Botryococcene - The Algal Biomass Hydrocarbon Oil
http://hdl.handle.net/2241/00153631
http://hdl.handle.net/2241/00153631fb98b677-0116-459b-91c2-aacc279d1d0c
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CS_3-1 (678.9 kB)
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CS_3-1-information (1.5 MB)
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Item type | Journal Article(1) | |||||
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公開日 | 2018-11-01 | |||||
タイトル | ||||||
タイトル | Site-Selective Hydrosilylation of Botryococcene - The Algal Biomass Hydrocarbon Oil | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Kawashima, Hidehisa
× Kawashima, Hidehisa× Umezawa, Mami× Kijima, Masashi |
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著者別名 |
川島, 英久
× 川島, 英久× 木島, 正志 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A biomass oil, botryococcene ((E)‐2,3,7,10,13,16,20,21‐octamethyl‐6,17‐dimethylene‐10‐vinyldocosa‐1,11,21‐triene), produced from microalga “Botryococcus braunii” was epoxidized by Prilezaev reaction using excess amount of m‐chloroperoxybenzoic acid under mild conditions for the purpose of applicative derivatizations of the oil. The oil underwent epoxidations at the C2,6,17,21‐positioned four vinylidenes and C11‐12 vinylene site‐selectively except the electronically inactive C10‐vinyl, giving the botryococcene pentaepoxide in high yield. | |||||
書誌情報 |
ChemistrySelect 巻 3, 号 1, p. 273-276, 発行日 2018-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 23656549 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1002/slct.201702686 | |||||
権利 | ||||||
権利情報 | ©2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | |||||
著者版フラグ | ||||||
値 | author | |||||
出版者 | ||||||
出版者 | wiley |