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Ruthenium(II) Complexes Having a Pincer‐Type Ligand with Two N‐Heterocyclic Carbene Moieties
http://hdl.handle.net/2241/00153369
http://hdl.handle.net/2241/001533699a119a57-028e-4c96-805d-732e4c539754
名前 / ファイル | ライセンス | アクション |
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ZAAC_644-14 (490.4 kB)
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Item type | Journal Article(1) | |||||
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公開日 | 2018-10-01 | |||||
タイトル | ||||||
タイトル | Ruthenium(II) Complexes Having a Pincer‐Type Ligand with Two N‐Heterocyclic Carbene Moieties | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Shimoyama, Yoshihiro
× Shimoyama, Yoshihiro× Ishizuka, Tomoya× Kotani, Hiroaki× Kojima, Takahiko |
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著者別名 |
石塚, 智也
× 石塚, 智也× 小谷, 弘明× 小島, 隆彦 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Two novel RuII complexes, having 2,2′‐bipyridyl and a pincer‐type methylene‐bridged N‐heterocyclic carbene (NHC) ligand, were synthesized and characterized to evaluate the effects of structural features of the complexes on their redox and photochemical properties. The methylene‐bridged NHC ligand coordinated in a meridional manner and the isopropyl groups on the NHC rings exhibited intramolecular CH/π interaction with the 2,2′‐bipyridyl ligand, which played a role to strongly maintain the distorted ligand structure. In addition, the two Ru complexes exhibited reversible redox waves in the cyclic voltammograms and they were oxidized by an electron‐transfer oxidant to afford RuIII complexes, which were characterized by EPR spectroscopy and theoretical analyses. | |||||
書誌情報 |
Zeitschrift für anorganische und allgemeine Chemie 巻 644, 号 14, p. 611-615, 発行日 2018-08 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 00442313 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00894185 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1002/zaac.201800104 | |||||
権利 | ||||||
権利情報 | This is the peer-reviewed version of the following article: ZAAC Volume644, Issue14, Pages 611-615 which has been published in final form at https://doi.org/10.1002/zaac.201800104. This article may be used for non-commercial purposes in accordance with Wiley-VCH Terms and Conditions for Self-Archiving. | |||||
権利 | ||||||
権利情報 | © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | |||||
著者版フラグ | ||||||
値 | author | |||||
出版者 | ||||||
出版者 | Wiley |