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Zigzag-Elongated Fused π-Electronic Core: A Molecular Design Strategy to Maximize Charge-Carrier Mobility
http://hdl.handle.net/2241/00153585
http://hdl.handle.net/2241/00153585a0e2c84c-531e-470d-96a0-c6d0f686374a
名前 / ファイル | ライセンス | アクション |
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AS_5-1700317 (2.1 MB)
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Item type | Journal Article(1) | |||||
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公開日 | 2018-10-22 | |||||
タイトル | ||||||
タイトル | Zigzag-Elongated Fused π-Electronic Core: A Molecular Design Strategy to Maximize Charge-Carrier Mobility | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Yamamoto, Akito
× Yamamoto, Akito× Murata, Yoshinori× Mitsui, Chikahiko× Ishii, Hiroyuki× Yamagishi, Masakazu× Yano, Masafumi× Sato, Hiroyasu× Yamano, Akihito× Takeya, Jun× Okamoto, Toshihiro |
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著者別名 |
石井, 宏幸
× 石井, 宏幸 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Printed and flexible electronics requires solution‐processable organic semiconductors with a carrier mobility (μ) of ≈10 cm2 V−1 s−1 as well as high chemical and thermal durability. In this study, chryseno[2,1‐b:8,7‐b′]dithiophene (ChDT) and its derivatives, which have a zigzag‐elongated fused π‐electronic core (π‐core) and a peculiar highest occupied molecular orbital (HOMO) configuration, are reported as materials with conceptually new semiconducting π‐cores. ChDT and its derivatives are prepared by a versatile synthetic procedure. A comprehensive investigation reveals that the ChDT π‐core exhibits increasing structural stability in the bulk crystal phase, and that it is unaffected by a variation of the transfer integral, induced by the perpetual molecular motion of organic materials owing to the combination of its molecular shape and its particular HOMO configuration. Notably, ChDT derivatives exhibit excellent chemical and thermal stability, high charge‐carrier mobility under ambient conditions (μ ≤ 10 cm2 V−1 s−1), and a crystal phase that is highly stable, even at temperatures above 250 °C. | |||||
書誌情報 |
Advanced Science 巻 5, 号 1, p. 1700317, 発行日 2017-11 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 21983844 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1002/advs.201700317 | |||||
権利 | ||||||
権利情報 | © 2017 The Authors. | |||||
権利 | ||||||
権利情報 | Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. | |||||
著者版フラグ | ||||||
値 | publisher | |||||
出版者 | ||||||
出版者 | WILEY |