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Formation and Isolation of a Four-Electron-Reduced Porphyrin Derivative by Reduction of a Stable 20π Isophlorin
http://hdl.handle.net/2241/00151254
http://hdl.handle.net/2241/0015125451cef202-cabe-4046-951c-4c0edd9634f0
名前 / ファイル | ライセンス | アクション |
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ACIE_57-7 (4.9 MB)
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Item type | Journal Article(1) | |||||
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公開日 | 2018-04-16 | |||||
タイトル | ||||||
タイトル | Formation and Isolation of a Four-Electron-Reduced Porphyrin Derivative by Reduction of a Stable 20π Isophlorin | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Suzuki, Wataru
× Suzuki, Wataru× Kotani, Hiroaki× Ishizuka, Tomoya× Shiota, Yoshihito× Yoshizawa, Kazunari× Kojima, Takahiko |
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著者別名 |
小谷, 弘明
× 小谷, 弘明× 石塚, 智也× 小島, 隆彦 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The two‐electron reduction of a diprotonated dodecaphenylporphyrin derivative by Na2S2O4 gave a corresponding isophlorin (Iph) selectively. Formation of Iph was confirmed by spectroscopic measurements and the isolation of tetramethylated Iph. Further reduction of Iph proceeded to form an unprecedented four‐electron‐reduced porphyrin (IphH2), which was fully characterized by spectroscopic and X‐ray crystallographic analysis. IphH2, with a unique conformation, could be oxidized to reproduce the starting porphyrin, resulting in a proton‐coupled four‐electron reversible redox system. | |||||
書誌情報 |
Angewandte Chemie international edition 巻 57, 号 7, p. 1973-1977, 発行日 2017-12 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1433-7851 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA0052535X | |||||
PubMed番号 | ||||||
識別子タイプ | PMID | |||||
関連識別子 | 29206356 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1002/anie.201711058 | |||||
権利 | ||||||
権利情報 | © 2018 Wiley-VCH Verlag GmbH &Co. KGaA, Weinheim | |||||
権利 | ||||||
権利情報 | This is the pre-peer reviewed version of the following article: Angew. Chem. Int. Ed. 2017,57,1973-1977, which has been published in final form at 10.1002/anie.201711058. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | |||||
著者版フラグ | ||||||
値 | author | |||||
出版者 | ||||||
出版者 | Wiley |