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Lewis Basicity of Nitrogen-Doped Graphite Observed by CO2 Chemisorption
http://hdl.handle.net/2241/00145331
http://hdl.handle.net/2241/00145331a37a3555-e64d-45da-abea-899a079aa416
名前 / ファイル | ライセンス | アクション |
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NRL_11-127 (1.5 MB)
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Item type | Journal Article(1) | |||||
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公開日 | 2017-02-28 | |||||
タイトル | ||||||
タイトル | Lewis Basicity of Nitrogen-Doped Graphite Observed by CO2 Chemisorption | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Kiuchi, Hisao
× Kiuchi, Hisao× Shibuya, Riku× Kondo, Takahiro× Nakamura, Junji× Niwa, Hideharu× Miyawaki, Jun× Kawai, Maki× Oshima, Masaharu× Harada, Yoshihisa |
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著者別名 |
近藤, 剛弘
× 近藤, 剛弘× 中村, 潤児× 丹羽, 秀治 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The characteristics of CO2 adsorption sites on a nitrogen-doped graphite model system (N-HOPG) were investigated by X-ray photoelectron and absorption spectroscopy and infrared reflection absorption spectroscopy. Adsorbed CO2 was observed lying flat on N-HOPG, stabilized by a charge transfer from the substrate. This demonstrated that Lewis base sites were formed by the incorporation of nitrogen via low-energy nitrogen-ion sputtering. The possible roles of twofold coordinated pyridinic N and threefold coordinated valley N (graphitic N) sites in Lewis base site formation on N-HOPG are discussed. The presence of these nitrogen species focused on the appropriate interaction strength of CO2 indicates the potential to fine-tune the Lewis basicity of carbon-based catalysts. | |||||
書誌情報 |
Nanoscale Research Letters 巻 11, 号 1277, 発行日 2016-03 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1931-7573 | |||||
PubMed番号 | ||||||
識別子タイプ | PMID | |||||
関連識別子 | 26951127 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1186/s11671-016-1344-6 | |||||
権利 | ||||||
権利情報 | © 2016 Kiuchi et al. | |||||
権利 | ||||||
権利情報 | Open Access This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made | |||||
著者版フラグ | ||||||
値 | publisher | |||||
出版者 | ||||||
出版者 | Springer |