WEKO3
アイテム
{"_buckets": {"deposit": "76f0a347-4ad7-482c-b28f-e8fdf8fa6e33"}, "_deposit": {"id": "30958", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "30958"}, "status": "published"}, "_oai": {"id": "oai:tsukuba.repo.nii.ac.jp:00030958", "sets": ["148", "1940", "2048"]}, "item_5_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2014", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "188", "bibliographicPageStart": "185", "bibliographicVolumeNumber": "1062", "bibliographic_titles": [{"bibliographic_title": "Journal of molecular structure"}]}]}, "item_5_creator_3": {"attribute_name": "著者別名", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "柴田, 知彦"}], "nameIdentifiers": [{"nameIdentifier": "106843", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "森, 龍也"}], "nameIdentifiers": [{"nameIdentifier": "157852", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "30598074", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://nrid.nii.ac.jp/ja/nrid/1000030598074"}, {"nameIdentifier": "0000003028", "nameIdentifierScheme": "筑波大学研究者総覧", "nameIdentifierURI": "http://trios.tsukuba.ac.jp/researcher/0000003028"}]}, {"creatorNames": [{"creatorName": "小島, 誠治"}], "nameIdentifiers": [{"nameIdentifier": "51", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "90134204", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://nrid.nii.ac.jp/ja/nrid/1000090134204"}, {"nameIdentifier": "0000000778", "nameIdentifierScheme": "筑波大学研究者総覧", "nameIdentifierURI": "http://trios.tsukuba.ac.jp/researcher/0000000778"}]}]}, "item_5_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "A liquid–glass transition and a crystalline state of pharmaceutical racemic ketoprofen were studied by Raman scattering and the broadband terahertz time-domain spectroscopy (THz-TDS) in the frequency range from 9 to 260 cm−1. The low-frequency Raman scattering spectra clearly shows the remarkable change related to a liquid–glass transition at about Tg = 267 K. After melt-quenching at liquid nitrogen temperature, a boson peak appears at about 16.5 cm−1 near and below Tg and the intensity of quasi-elastic scattering related to structural relaxation increases markedly on heating. The crystalline racemic ketoprofen of “conformer A” shows the noncoincidence effect of mode frequencies below 200 cm−1 between Raman scattering spectra and dielectric spectra observed by THz-TDS.", "subitem_description_type": "Abstract"}]}, "item_5_publisher_27": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Elsevier"}]}, "item_5_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1016/j.molstruc.2014.01.050", "subitem_relation_type_select": "DOI"}}]}, "item_5_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "© 2014 Elsevier B.V. NOTICE: this is the author’s version of a work that was accepted for publication in Journal of molecular structure. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of molecular structure, Volume 1062 (2014) DOI:10.1016/j.molstruc.2014.01.050"}]}, "item_5_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_5_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0022-2860", "subitem_source_identifier_type": "ISSN"}]}, "item_5_source_id_9": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00702852", "subitem_source_identifier_type": "NCID"}]}, "item_5_subject_20": {"attribute_name": "NIIサブジェクト", "attribute_value_mlt": [{"subitem_subject": "基礎工学・応用物理学", "subitem_subject_scheme": "Other"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Shibata, Tomohiko"}], "nameIdentifiers": [{"nameIdentifier": "106838", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Igawa, Hikaru"}], "nameIdentifiers": [{"nameIdentifier": "106839", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kim, Tae Hyun"}], "nameIdentifiers": [{"nameIdentifier": "106840", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Mori, Tatsuya"}], "nameIdentifiers": [{"nameIdentifier": "106841", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kojima, Seiji"}], "nameIdentifiers": [{"nameIdentifier": "106842", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2014-06-12"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "JMS_1062.pdf", "filesize": [{"value": "1.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 1100000.0, "url": {"label": "JMS_1062", "url": "https://tsukuba.repo.nii.ac.jp/record/30958/files/JMS_1062.pdf"}, "version_id": "500137a2-4f3d-441c-aade-553b14265d22"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Glass transition dynamics of anti-inflammatory ketoprofen studied by Raman scattering and terahertz time-domain spectroscopy", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Glass transition dynamics of anti-inflammatory ketoprofen studied by Raman scattering and terahertz time-domain spectroscopy"}]}, "item_type_id": "5", "owner": "1", "path": ["148", "1940", "2048"], "permalink_uri": "http://hdl.handle.net/2241/00121474", "pubdate": {"attribute_name": "公開日", "attribute_value": "2014-06-12"}, "publish_date": "2014-06-12", "publish_status": "0", "recid": "30958", "relation": {}, "relation_version_is_last": true, "title": ["Glass transition dynamics of anti-inflammatory ketoprofen studied by Raman scattering and terahertz time-domain spectroscopy"], "weko_shared_id": 5}
Glass transition dynamics of anti-inflammatory ketoprofen studied by Raman scattering and terahertz time-domain spectroscopy
http://hdl.handle.net/2241/00121474
http://hdl.handle.net/2241/00121474b5f28f21-72df-45ec-8010-9b839cf728bb
名前 / ファイル | ライセンス | アクション |
---|---|---|
JMS_1062 (1.1 MB)
|
|
Item type | Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2014-06-12 | |||||
タイトル | ||||||
タイトル | Glass transition dynamics of anti-inflammatory ketoprofen studied by Raman scattering and terahertz time-domain spectroscopy | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Shibata, Tomohiko
× Shibata, Tomohiko× Igawa, Hikaru× Kim, Tae Hyun× Mori, Tatsuya× Kojima, Seiji |
|||||
著者別名 |
柴田, 知彦
× 柴田, 知彦× 森, 龍也× 小島, 誠治 |
|||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A liquid–glass transition and a crystalline state of pharmaceutical racemic ketoprofen were studied by Raman scattering and the broadband terahertz time-domain spectroscopy (THz-TDS) in the frequency range from 9 to 260 cm−1. The low-frequency Raman scattering spectra clearly shows the remarkable change related to a liquid–glass transition at about Tg = 267 K. After melt-quenching at liquid nitrogen temperature, a boson peak appears at about 16.5 cm−1 near and below Tg and the intensity of quasi-elastic scattering related to structural relaxation increases markedly on heating. The crystalline racemic ketoprofen of “conformer A” shows the noncoincidence effect of mode frequencies below 200 cm−1 between Raman scattering spectra and dielectric spectra observed by THz-TDS. | |||||
書誌情報 |
Journal of molecular structure 巻 1062, p. 185-188, 発行日 2014 |
|||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0022-2860 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00702852 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1016/j.molstruc.2014.01.050 | |||||
権利 | ||||||
権利情報 | © 2014 Elsevier B.V. NOTICE: this is the author’s version of a work that was accepted for publication in Journal of molecular structure. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of molecular structure, Volume 1062 (2014) DOI:10.1016/j.molstruc.2014.01.050 | |||||
著者版フラグ | ||||||
値 | author | |||||
出版者 | ||||||
出版者 | Elsevier |